1990
DOI: 10.1364/ao.29.004225
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Collinear photothermal deflection spectroscopy with light-scattering samples

Abstract: An analytical model that incorporates effects of light scattering was developed for dual-beam photothermal deflection spectroscopy. Thermal gradients induced by a modulated excitation beam deflect an optical probe beam which was treated as being of finite dimensions. Mechanisms by which thermal gradients produce refractive index gradients are discussed, with an explicit expression for dn/dT being derived. Experimental studies with suspensions of small latex particles in Nd(3+) solutions demonstrated that the m… Show more

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Cited by 38 publications
(21 citation statements)
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“…The fluorescence signal is subsequently detected by an optical spectrum analyzer. For a measurement of the temperature change in the gas cell induced by the cooling beam, we employed thermal deflection spectroscopy [17,18]. For this measurement of the cooling, the Ti:sapphire laser was tuned to a wavelength of 785 nm, far to the red of the unperturbed potassium D-lines (that is 766 nm and 770 nm, for the D2-and D1lines respectively).…”
Section: Methodsmentioning
confidence: 99%
“…The fluorescence signal is subsequently detected by an optical spectrum analyzer. For a measurement of the temperature change in the gas cell induced by the cooling beam, we employed thermal deflection spectroscopy [17,18]. For this measurement of the cooling, the Ti:sapphire laser was tuned to a wavelength of 785 nm, far to the red of the unperturbed potassium D-lines (that is 766 nm and 770 nm, for the D2-and D1lines respectively).…”
Section: Methodsmentioning
confidence: 99%
“…This can be performed by solving the temperature gradient developed in a beam deflection model. 21) In the present setup the equations for heat conduction in the wire, fluid, and nanoparticles are established using a cylindrical coordinate system in dimensionless forms as 1 @u w ðr; Þ @ ¼ @ 2 u w ðr; Þ @r 2 þ 1 r @u w ðr; Þ @r þ gðr; Þ; ð1Þ…”
Section: Thermal and Laser Beam Displacement Modelsmentioning
confidence: 99%
“…The 1D approximation requires the condition of the probe beam radius to be much smaller than the excitation beam radius [16]. Then, each part of the PB interacts with approximately the same thermal gradients and undergoes the same deflection [17].…”
Section: Methodsmentioning
confidence: 99%