In this paper the problem is posed of determining the physically-meaningful asymptotic orderings holding for the statistical description of a large N −body system of hard spheres, i.e., formed by N ≡ 1 ε ≫ 1 particles, which are allowed to undergo instantaneous and purely elastic unary, binary or multiple collisions. Starting point is the axiomatic treatment recently developed [Tessarotto et al., 2013 and the related discovery of an exact kinetic equation realized by Master equation which advances in time the 1−body probability density function (PDF) for such a system. As shown in the paper the task involves introducing appropriate asymptotic orderings in terms of ε for all the physically-relevant parameters. The goal is that of identifying the relevant physically-meaningful asymptotic approximations applicable for the Master kinetic equation, together with their possible relationships with the Boltzmann and Enskog kinetic equations, and holding in appropriate asymptotic regimes. These correspond either to dilute or dense systems and are formed either by small-size or finite-size identical hard spheres, the distinction between the various cases depending on suitable asymptotic orderings in terms of ε.
-INTRODUCTIONIn a series of papers [1][2][3][4][5][6][7] (see also Refs. [8,9]) a new kinetic equation has been established for hard sphere systems subject to elastic instantaneous collisions, denoted as Master kinetic equation. Its basic features are that, unlike the Boltzmann and Enskog kinetic equations [11][12][13], the same equation and its corresponding Master collision operator are exact, i.e., they hold for an arbitraryN −body hard-sphere system S N which is isolated, namely for which the number of particles (N ) is constant, while furthermore that its solutions are entropy-preserving [6] and globally defined [7]. Concerning, in particular, the first feature this means that in such a context S N is allowed to have an arbitrary finite number N of finite-size and finite-mass hard spheres, namely each one characterized by finite diameter σ > 0 and mass m > 0. In addition, by assumption S N is immersed in a bounded configuration domain Ω, subset of the Euclidean space R 3 which has a finite canonical measure L 3 o ≡ µ(Ω) > 0 (L o denoting a finite configuration-domain characteristic scale length) and is endowed with a stationary and rigid boundary ∂Ω. However, the total volume occupied by hard-spheres cannot exceed the configuration-space volume. Hence, the parameters N, L o and σ must necessarily satisfy the inequalitydenoting the volume of a single hard sphere and ∆ the global diluteness parameter. For such an equation the particle correlations appearing through the 2−body probability density function (PDF) are exactly taken into account by means of suitably-prescribed 1− and 2−body occupation coefficients which are position-dependent only. These peculiar features follow uniquely as a consequence of the new approach to classical statistical mechanics developed in Refs. [1][2][3] and referred to as "ab initio...