Nitryl Perchlorate, NO2CIO4. The sample was taken directly from an unpurified reaction product; however, analysis for total acid content indicated high purity7. No further purification was attempted because of the extreme hygroscopicity7 of the material. The crystals are monoclinic, space group c2/c, a = 9.25 A., b = 6.99 A., c = 7.34 A.,/3 = 113.5°( 4).Potassium Formate, HCOOK. Fisher Scientific Co. reagent grade material was used after re crystallization from methanol.Sodium Methyl Carbonate, NaCH3-C03. The sample was prepared at Gallery Chemical Co. and submitted in pure form. Intensities were measured with the diffractometer.Sodium Metaborate, NaBCh. The sample was prepared at Gallery Chemical Co. by dehydration of carefully purified sodium metaborate tetrahydrate. The crystals are rhombohedral, space group R3c, a -11.93 A., c = 6.46 A. (8,5,6).Sodium Tetrafluoroborate (1-), Na-BF4. The sample was prepared at Gallery Chemical Co. and was submitted in pure form. The crystals are orthorhombic with the following reported call dimensions: a = 6.25 A.