Hierarchical, mesoporous CuCo 2 O 4 nanograss has been synthesized on copper foam using a simple and cost-effective hydrothermal approach followed by a post-annealing treatment. The electrodes made from the novel nanoarchitecture exhibit multi-functional electrochemical performance. They deliver an excellent specific capacitance of 796 F g -1 at a current density of 2 A g -1 in a 2 M KOH aqueous solution and a long-term cyclic stability of 94.7% capacitance retention after 5000 cycles.When applied to electro-catalytic oxidation of methanol, the current density of the CuCo 2 O 4 /Cu foam electrode in 1 M KOH mixed with 0.5 M methanol is maintained up to 27.6 A g -1 . The superior electrochemical performances are mainly due to the unique one dimensional porous acicular architecture with very large surface area and 2 porosity grown on highly conductive Cu substrate, offering faster ion/electron transfer, an improved reactivity and an enhanced structural stability. The fabrication strategy presented here is simple, cost-effective and scalable, which can open new avenues for large-scale applications of the novel materials in energy storage.Fig. 5 (a, b) Low-magnification and high-magnification TEM images of an acicular CuCo 2 O 4 nanograss leaf; (c) corresponding SAED pattern; and (d) energy-dispersive X-ray spectrum of the elements Co, Cu and O.