Gray cast iron (GJL) is known for its excellent damping property and high thermal conductivity, thanks to its unique lamellar graphite and pearlite structure. In a recent study, laser metal deposition (LMD) was explored as a potential process to enhance the corrosion resistance and wear mechanism of this tribological system. The focus was on laser cladding of gray cast iron using two different of stainless-steel materials, namely 430L and 316L, combined with TiC and WC particles. To create the samples, a multilayer coating system was employed. A comparative analysis of the microstructures was performed to understand the interaction of the laser beam with the material (composite materials). Surface properties were then characterized using light microscopy and electron microscopy (SEM) before and after subjecting the samples to a shock corrosion test, simulating automotive conditions. Additionally, phase analyses were performed at the interfaces between the coatings and the substrate, with particular attention given to the behavior of the graphite lamellae at these interfaces. This study aims to provide valuable insights into the potential improvements that can be achieved through laser cladding on gray cast iron, specifically in terms of corrosion resistance and wear mechanisms. By analyzing the microstructures and surface properties, researchers can gain a better understanding of the performance and durability of the coated samples.