Advancing lithium-ion batteries (LIBs) in both design and usage is key to promoting electrification in the coming decades to mitigate human-caused climate change. Inadequate understanding of LIB degradation is an important bottleneck that limits battery durability and safety. Here, we propose hybrid physics-based and data-driven modeling for online diagnosis and prognosis of battery degradation. Compared to existing battery modeling efforts, we aim to build a model with physics as its backbone and statistical learning techniques as enhancements. Such a hybrid model has better generalizability and interpretability together with a wellcalibrated uncertainty associated with its prediction, rendering it more valuable and relevant to safety-critical applications under realistic usage scenarios.
Lithium-ion batteries, electrification and climate changeBy reducing greenhouse gas emissions to mitigate climate change, electrification plays an essential role in distributed energy consumption, such as electric vehicles, and in centralized power grid supply, where energy storage facilities are needed to mediate the mismatch between load requirements and intermittent renewable energy sources such as sunlight, wind, and tide. In such applications, rechargeable lithium-ion batteries (LIBs) [1] are an increasingly pivotal technology for energy storage and conversion. Therefore, much effort has been devoted in the past decades towards LIB materials development and design improvement [2, 3], modeling [4], and real-time control [5].A common key aspect underlying these endeavors is understanding, detecting, and predicting battery degradation [6], of which the effectiveness will directly impact the performance, durability, safety, and cost of LIBs. In this project, we propose the approach of hybrid physics-based and data-driven modeling for online diagnosis and prognosis, by which we mean estimation of battery state of health (SOH) and prediction of remaining useful life (RUL), respectively, under typical usage patterns. We would like to emphasize two main threads of model development. First, we want to minimize reliance on historical usage data in diagnosis and prognosis, which will enhance the applicability and practicality of the approach. Second, we make heavy use of known physical knowledge of both charge/discharge cycling and degradation to reduce the amount of training data required, and increase the generalizability as well as interpretability of the modeling approach.
Gaps in past research on battery degradation predictionWe first categorize current methodologies for SOH estimation, RUL prediction and degradation prognosis along three main dimensions, all of which affect their relevance to practical usage scenarios, and then review where various lines of past research lie in this landscape.