The effects of acidic components
and asphaltenes on the dilational
rheological properties of hydrophobically modified polyacrylamide
(APP5) have been measured as a function of the time, frequency, bulk
concentration, and interfacial pressure by means of a drop shape analysis
method. It is established that acidic components and asphaltenes play
an important role on the interfacial properties of the APP5/crude
oil component mixture at water–kerosene interface. With the
addition of acidic components, the dilational modulus of the mixture
not only increases with time but is also higher at low concentrations
and runs through a maximum at a lower concentration compared to pure
APP5. Also, the phase angle of APP5/acidic components is lower compared
to pure APP5. The results indicate that the appearance of more elastic
films because of the mixed adsorption of acidic components and APP5
molecules. The addition of asphaltenes does not influence the interfacial
properties of APP5 at high APP5 concentrations. However, one can observe
changes of the interfacial tension and the dilational modulus with
the addition of asphaltenes at lower APP5 concentrations. It can be
concluded that the behaviors of interfacial layers of the APP5/asphaltene
mixture are controlled by APP5 molecules in competition with the asphaltenes
at the interface.