Evaluation of performance parameters, emission and brake specific fuel consumption (BSFC) were made for different blends of solketal in soybean biodiesel with 9%, 10%, 12%, 15% of solketal (volume to volume). These experiments were performed on a single-cylinder water-cooled diesel engine at different speeds and 50% load conditions. In comparison to pure diesel, it was observed that soybean biodiesel and its blends with solketal were higher BSFC. On the addition of solketal to biodiesel higher oxides of nitrogen (NOx) and carbon dioxide (CO2) emissions were reported for all the blends. total hydro carbon (THC) and carbon mono-oxide (CO) emissions were found lower for soybean biodiesel and it’s all four blends as compared to pure diesel and further decreases with the increase in solketal percentage in a blend. A decrease in CO and THC emissions were also observed with the increase in percentage of Solketal fuels. Solketel was found suitable and as an effective additive for biodiesel blends.