Comparative analysis of chromatography dynamic models in predicting the plate height contributed by interphase mass transfer

Yan, Xiaohong; Wang, Qiuwang

doi:10.1016/j.ces.2013.10.011

Cited by 2 publications

(1 citation statement)

References 27 publications

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“…5 (2).2021 the column estimation, rather than on the on the main parameters of peaks. For example, a general rate model permitted reasonably accurate predictions for plug flow through open columns, but it was inaccurate for pressure driven flow cases [7]; the volume averaging model was accurate for some columns [8]. To the best of our knowledge, the question of how conditions of analysis influence the number of theoretical plates was not investigated, as the number of theoretical plates was considered mainly for control of the efficiency of a column [9].…”

Section: Introductionmentioning

confidence: 99%

Influence of Conditions of GC- Flame Ionization Detector Analysis on Parameters of Peaks in Highly Concentrated Compounds

Yarmolinsky¹,

Yarmolinsky²,

Ben‐Shabat

et al. 2021

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The aim of this research was to investigate an influence of flow velocity on the main parameters (retention time, tailing factor, relative area and number of theoretical plates) of peaks belonging to volatile compounds in the GC-Flame ionization detector analysis. Our results showed that as the flow increases, the retention time declines significantly (p<0.01). The other above-mentioned parameters of peaks also change depending on the characteristics of the solvents. The obtained results provide a platform for increasing accuracy of impurity tests for many volatile compounds and development of novel methods of analysis.

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Section: Introductionmentioning

confidence: 99%