Single crystal of bismuth tellurite Bi 2 TeO 5 (BTO) doped with trivalent thulium (Tm 3+ ) was grown by the Czochralski method and investigated by spectroscopic techniques (absorption, emission). Absorption and emission of the Tm:BTO crystal collected in the VIS-IR spectral range are presented. Spectroscopic features were investigated as a function of the excitation light polarisation (E//X, Y, and Z axis of optical indicatrix) and sample temperature. The oscillator strength of the , P Y = 6.8 × 10 −6 and P Z = 5.9 × 10 −6 that gives a mean value P mean = 5.8 × 10 H 6 luminescence at around 1.8 µm was too weak to be acquired from the low concentrated sample. However, based on optical data it was possible to estimate the radiative probability A rad of this transition and the 3 F 4 radiative lifetime. The resultant values are: A rad = 668 ± 0.4 s −1 and τ rad = 1.5 ms.