The effect of surface passivation using ͑NH 4 ͒ 2 S and ͑NH 4 ͒ 2 S/P 2 S 5 on a AlGaN/GaN-based metal-semiconductor-metal diode above a two-dimensional electron gas ͑MSM-2DEG͒ varactor was investigated. The surface property, capacitance ratio ͑C max /C min ͒, and leakage current of the prepared samples were studied before and after treatments using X-ray photoelectron spectroscopy and capacitance-voltage and current-voltage analyses. It showed that the ͑NH 4 ͒ 2 S/P 2 S 5 -treated sample had the most excellent surface state and C max /C min and the least leakage current because of either reduced native oxide or deposited phosphorus compounds only provided by ͑NH 4 ͒ 2 S/P 2 S 5 and sulfide upon the surface, also validated by having the highest sheet carrier density. Hence, these promising results promote further potential for varactor applications.The metal-semiconductor-metal diode above a two-dimensional electron gas ͑MSM-2DEG͒ has shown its potential as a varactor that can be easily integrated with high electron mobility transistor devices. In addition, its voltage-dependent capacitance ratio is much larger than that of conventional varactor diodes and can be tuned by electrode geometry in contrast to the conventional p-n, Schottky, or heterostructure diodes where the ratio is only defined by the layer structure. 1-3 After the development of SiO 2 /AlGaN/GaN-based double metal-oxide-semiconductor heterojunction capacitors with reduced leakage current, the MSM-2DEG based on this layer structure was proposed as a robust radio-frequency switch. 4 Most of these applications seek the large capacitance ratio. However, except by tuning the electrode geometry, few investigations on the improvement of capacitance ratio obtaining the superior varactor performance are published. 5,6 Marso et al. 5 reported that metal-oxidesemiconductor heterojunction field effect transistor ͑MOSHFET͒ MSM with an oxide layer between the metal and the semiconductor decreased the C max and made the capacitance-voltage ͑C-V͒ characteristic asymmetric even though it could reduce the leakage current. Besides, they also indicated that better controllable capacitance ratio and stable C-V properties could be obtained in the heterostructure field effect transistor ͑HFET͒ MSM without an oxide layer between the metal and the semiconductor, but it was with a worse leakage current. It was reported that sulfur treatment is very effective in reducing the surface states and surface recombination velocity in III-V compound semiconductors. 7-12 Of the various sulfur treatments, only the ͑NH 4 ͒ 2 S x treatment achieved promising results due to its capacity to etch the native oxide and the GaAs surface and to tie up the dangling bonds with sulfur on a freshly exposed prismatic GaAs surface. Although increasing immersion time promotes the performance, longer immersion time causes a higher surface roughness and a decline in the mobility of electrons by high sulfide contamination and chemical reaction. Hence, hot ͑NH 4 ͒ 2 S x treatment or ͑NH 4 ͒ 2 S x + UV ...