Comparative study of binding interactions between porphyrin systems and aromatic compounds of biological importance by multiple spectroscopic techniques: A review

Makarska-Białokoz, Magdalena

doi:10.1016/j.saa.2018.04.037

Cited by 9 publications

(1 citation statement)

References 170 publications

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“…They are a type of stable, inert molecule that can be metalated to produce a variety of synthetic, natural compounds. These porphyrins produce noncovalent interaction systems with other chemical agents that have the appropriate shape [5]. Structure and function are provided by the unique optical, electrochemical, and photo catalytic characteristics of porphyrins and its derivatives, which have defined geometry and chemistry.…”

Section: Introductionmentioning

confidence: 99%

Predictive analytics of conductance and HOMO-LUMO gaps with topological descriptors of porphyrin nanosheets

Junias,

Clement

2023

Phys. Scr.

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Porphyrins are planar tetrapyrolic aromatic molecules that serve as a host for the formation of metal coordination complexes, which enable additional capabilities. The 2D porphyrin derivative sheets attracted interest due to their versatility and capacity to interact with other chemicals due to the existence of a core metal ion. Topological descriptors are employed as a predictive technique to determine the physical, chemical, and structural characteristics of molecules by considering the molecular structure of compounds as molecular graphs. This paper investigates the degree and degree sum based descriptors of some potential porphyrin derivative nanosheets, using the edge partition method. We also demonstrate a predictive model for analyzing the electrical conductance of porphyrin derivative nanosheets using degree and degree sum based topological descriptors. Furthermore, the Shannon's information entropies of these porphyrin derivatives are investigated, and the HOMO-LUMO gap of these nanostructures is predicted using these entropy.

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Section: Introductionmentioning

confidence: 99%

Predictive analytics of conductance and HOMO-LUMO gaps with topological descriptors of porphyrin nanosheets

Junias,

Clement

2023

Phys. Scr.

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Synthesis, Photophysics, Computational Approaches, and Biomolecule Interactive Studies of Metalloporphyrins Containing Pyrenyl Units: Influence of the Metal Center

et al. 2022

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A classical methodology to design free-base meso-tetra-(1pyrenyl)porphyrin (H 2 TPyrP) and their corresponding metalloporphyrins containing Zn(II), Cu(II), Ni(II), Co(III), and Mn(III) was described. These porphyrins were characterized in terms of structure, photophysical, and interactions profile with calfthymus deoxyribonucleic acid (CT-DNA) and bovine serum albumin (BSA). H 2 TPyrP exhibited five characteristic bands in the visible wavelength: Soret (432 nm) and Q-bands (520-650 nm range), while the metalloporphyrins showed some spectrum shifts according to the nature of the ion, which were also explored by time-dependent density functional theory (TD-DFT) calculations. The fluorescence and singlet oxygen quantum yield (Φ fl , Φ Δ , respectively) decreased with the presence of metal species in the porphyrin core. The porphyrins interact spontaneously via a ground-state association in the minor groove of CT-DNA following the increasing order of binding: CuTPyrP < H 2 TPyrP < CoTPyrP < MnTPyrP < NiTPyrP < ZnTPyrP, while for BSA the suitable complex geometry for Co(III) and Mn(III) complexes increased the binding capacity.

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Porphyrins with Phenolic Fragments at the Periphery of the Macrocycle as Perspective Antioxidants, Cytoprotectors and Heavy Metal Scavengers

Kolyada

Осипова

Берберова

et al. 2021

Chem Heterocycl Comp

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Comparative study of binding interactions between porphyrin systems and aromatic compounds of biological importance by multiple spectroscopic techniques: A review

Cited by 9 publications

References 170 publications

Predictive analytics of conductance and HOMO-LUMO gaps with topological descriptors of porphyrin nanosheets

Predictive analytics of conductance and HOMO-LUMO gaps with topological descriptors of porphyrin nanosheets

Synthesis, Photophysics, Computational Approaches, and Biomolecule Interactive Studies of Metalloporphyrins Containing Pyrenyl Units: Influence of the Metal Center

Porphyrins with Phenolic Fragments at the Periphery of the Macrocycle as Perspective Antioxidants, Cytoprotectors and Heavy Metal Scavengers

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