The high density and viscosity of heavy crude oil seriously
affect
the production and transportation processes, and surfactant emulsification
and viscosity reduction technology are regarded as the ideal methods
to enhance oil recovery of heavy oil reservoirs. In the present paper,
sodium dodecyl sulfate and sodium dodecyl ether sulfate are used to
study the effects of the number of introduced ethoxy (EO) groups on
the emulsification and viscosity reduction of surfactants through
the experimental method, molecular dynamics simulation, and quantum
chemical calculations. The results of optical microscopy and viscosity
measurement show that the surfactants can change the emulsion type
of heavy oil to cause a remarkable reduction of emulsion viscosity.
Then, the molecular density, interfacial thickness, and hydrogen bond
relaxation time are computed to study the change of the properties
of an interfacial film with additional surfactants. The interaction
among surface-active substances is evaluated by radial direction functions
and the independent gradient model based on the Hirshfeld partition
method, which is confirmed through the steered molecular dynamics
simulation method. The simulation results indicate that the surfactants
containing more EO groups show better adsorption behavior to enhance
the interfacial hydrophilicity and destroy stacking structures among
asphaltene and resin molecules, which is conducive to the emulsification
and viscosity reduction process. This work presents a nanometer view
of the effects of the number of introduced EO groups on the emulsification
and viscosity reduction mechanisms of anionic–nonionic surfactants.