Our community is currently dealing with issues such as rising electricity costs, pollution, and global warming. Scientists are working to improve energy harvesting-based power generators in order to reduce their impacts. The Seebeck effect has been used to illustrate the capacity of thermoelectric generators (TEGs) to directly convert thermal energy to electrical energy. They are also ecologically beneficial since they do not include chemical products, function quietly because they lack mechanical structures and/or moving components, and may be built using different fabrication technologies such as 3D printing, silicon technology, and screen printing etc. TEGs are also position-independent, have a long operational lifetime, and can be integrated into bulk and flexible devices. This review gives further in investigation of TEGs, beginning with a full discussion of their operating principle, kinds, materials utilized, figure of merit, and improvement approaches, which include various thermoelectric material arrangements and utilised technologies. This paper also discusses the use of TEGs in a variety of disciplines such as automobile and biomedical.