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Abstract:La(OH) 3 -modified exfoliated vermiculites were fabricated, characterized, and investigated for phosphate removal in batch tests for the first time. The BET surface area of the La 5 EV adsorbent, which was synthesized in the solution consisting of 5.00 mmol/g La/exfoliated vermiculite (EV), was significantly increased, accompanied with a larger pore diameter and greater total pore volume, as compared with the unmodified EV. The phosphate adsorption capacity of La 5 EV was approximately one order of magnitude higher than that of EV. Effects of initial phosphate concentration, contact time, temperature, pH, and 2 co-existing ions on the adsorption capacity of La 5 EV were investigated in detail. The experimental equilibrium data were fitted better by using the Langmuir model (maximum adsorption capacity of 79.6 mg P/g) than the Dubinin-Radushkevich or the Freundlich model, suggesting that the adsorption feature be monolayer. Meanwhile, the phosphate adsorption kinetics could be well described by the pseudo-second-order model, and the adsorption process might be controlled by boundary layer (film) diffusion. ∆G°, ∆H° and ∆S° were also determined, in which it was found that the phosphate adsorption , and SO 4 2-had neglectable effects on its phosphate removal capacities. In the synthetic secondary treated wastewater with a low phosphate concentration of 2 mg P/L, 97.9 % of its final adsorption capacity reached in the first 10 min and the phosphate concentration dramatically decreased below 50 µ g P/L. The spent La 5 EV could be regenerated and reused in phosphate adsorption; that could remove more than 70 % phosphate in the 3 rd adsorption-desorption cycle.