2007
DOI: 10.1134/s107032840708012x
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Complex formation of heavy metals with 4-(2-pyridy-lazo)resorcinol chemically immobilized on silica gel

Abstract: The complexing properties of modified silica with 4-(2-pyridylazo)resorcinol covalently immobilized by the Mannich reaction are studied with respect to heavy metals. This adsorbent can be used for the preconcentration of heavy metal ions due to its satisfactory kinetic characteristics. The structures of the heavy metal complexes with 4-(2-pyridylazo)resorcinol immobilized on the silica gel surface are studied by ESR and diffuse reflectance spectroscopy.

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Cited by 2 publications
(2 citation statements)
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“…37 At pH 6.8 ± 7, it quantitatively adsorbs some toxic metal ions such as Pb II , Cd II and Ni II . This adsorbent is promising for solid-phase preconcentration of heavy metals in the analyses of various natural specimens.…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…37 At pH 6.8 ± 7, it quantitatively adsorbs some toxic metal ions such as Pb II , Cd II and Ni II . This adsorbent is promising for solid-phase preconcentration of heavy metals in the analyses of various natural specimens.…”
Section: Methodsmentioning
confidence: 99%
“…It is because in thiosulfate solution, silver exists initially as complex anions that undergo stepwise dissociation to Ag + (Scheme 19). The adsorption of other noble metals that exist in the form of complex chlorometallate anions under these conditions and possibly the [Ag(S 2 O 3 )] 37 anion proceeds according to the anion exchange mechanism. The anion exchange ability of polymer 28 is due to the ability of its functional group to exist in the betaine form (Scheme 20).…”
Section: Scheme 18mentioning
confidence: 99%