Comprehensive screening of 63 coloring agents in cosmetics using matrix solid-phase dispersion and ultra-high-performance liquid chromatography coupled with quadrupole-Orbitrap high-resolution mass spectrometry

Chen, Meng; Bai, Hua; Zhai, Junfeng; Meng, Xianshuang; Guo, Xiangyu; Wang, Chun; Wang, Penglong; Lei, Haimin; Niu, Zengyuan; Ma, Qiang

doi:10.1016/j.chroma.2019.01.003

Cited by 18 publications

(17 citation statements)

References 51 publications

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“…Regarding the elution solvent, ethyl acetate showed the highest extraction efficiency for most of the target compounds before GC analysis [65,69,70,73,74], whereas MeOH was the preferred elution solvent for μ-MSPD extractions before LC analysis [66][67][68]. The use µ-MSPD was subsequently successfully applied for the determination of other cosmetic ingredients including dyes, fragrances, preservatives [66][67][68][69][70][71], as well as for the multianalyte determination of a high number of allowed and restricted ingredients, in addition to banned compounds such as glucocorticoids [72,73,75]. Recently, this miniaturized approach was also applied to extract impurities or unexpected compounds such as polycyclic aromatic hydrocarbons (PAHs), fungicides, nitrosamines, or alkylphenol ethoxylates (APEOs) from cosmetics formulations.…”

Section: Matrix Solid-phase Dispersion (Mspd)mentioning

confidence: 99%

Section: Matrix Solid-phase Dispersion (Mspd)mentioning

confidence: 99%

“…µ-MSPD was subsequently successfully applied for the determination of other cosmetic ingredients including dyes, fragrances, preservatives [ 66 , 67 , 68 , 69 , 70 , 71 ], as well as for the multianalyte determination of a high number of allowed and restricted ingredients, in addition to banned compounds such as glucocorticoids [ 72 , 73 , 75 ]. Recently, this miniaturized approach was also applied to extract impurities or unexpected compounds such as polycyclic aromatic hydrocarbons (PAHs), fungicides, nitrosamines, or alkylphenol ethoxylates (APEOs) from cosmetics formulations.…”

Section: Sample Preparation Strategies For Cosmetics Analysismentioning

confidence: 99%

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Recent Advances in Sample Preparation for Cosmetics and Personal Care Products Analysis

et al. 2021

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The use of cosmetics and personal care products is increasing worldwide. Their high matrix complexity, together with the wide range of products currently marketed under different forms imply a challenge for their analysis, most of them requiring a sample pre-treatment step before analysis. Classical sample preparation methodologies involve large amounts of organic solvents as well as multiple steps resulting in large time consumption. Therefore, in recent years, the trends have been moved towards the development of simple, sustainable, and environmentally friendly methodologies in two ways: (i) the miniaturization of conventional procedures allowing a reduction in the consumption of solvents and reagents; and (ii) the development and application of sorbent- and liquid-based microextraction technologies to obtain a high analyte enrichment, avoiding or significantly reducing the use of organic solvents. This review provides an overview of analytical methodology during the last ten years, placing special emphasis on sample preparation to analyse cosmetics and personal care products. The use of liquid–liquid and solid–liquid extraction (LLE, SLE), ultrasound-assisted extraction (UAE), solid-phase extraction (SPE), pressurized liquid extraction (PLE), matrix solid-phase extraction (MSPD), and liquid- and sorbent-based microextraction techniques will be reviewed. The most recent advances and future trends including the development of new materials and green solvents will be also addressed.

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Section: Matrix Solid-phase Dispersion (Mspd)mentioning

confidence: 99%

Section: Matrix Solid-phase Dispersion (Mspd)mentioning

confidence: 99%

Section: Sample Preparation Strategies For Cosmetics Analysismentioning

confidence: 99%

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Recent Advances in Sample Preparation for Cosmetics and Personal Care Products Analysis

et al. 2021

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“…e elution procedure is that the transferred analytes are eluted from dispersant or adsorbent. erefore, MSPD presents outstanding performance on agricultural residues [16], cosmetics [17], and air pollution [18] with the highlights of green environmental protection, simple process, satisfactory recovery, and high efficiency. At the same time, it is rarely reported that MSPD is applied to volatile components in TCM [19].…”

Section: Introductionmentioning

confidence: 99%

Binary Eluent Based Vortex-Assisted Matrix Solid-Phase Dispersion for the Extraction and Determination of Multicomponent from Musk by Gas Chromatography-Mass Spectrometry

Wang

Shang

Liang

et al. 2021

Journal of Analytical Methods in Chemistry

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A green, flexible, and effective strategy was proposed to quantify four target compounds (muscone, ethyl palmitate, ethyl oleate, and ethylparaben) from musk by binary eluent based vortex-assisted matrix solid-phase dispersion (MSPD) extraction coupled with GC/MS. Single-factor tests and orthogonal design were employed to optimize the MSPD parameters. In addition, the binary eluent system, methanol, and ethyl acetate 3 : 7 (v/v) were used to extract the target analytes. Finally, C18 was applied as the easily available dispersant and the sample powder was ground for 2 min. Thereafter, the mixture was rapidly extracted with the binary eluents under whirling for 3 min. Eventually, the analysis of the samples was completed within 12 min by GC/MS. All correlation coefficients (r) of four targets were more than 0.9991. The recoveries of all target compounds ranged from 92.8% to 101% while their RSDs were less than 6.94%. There was no significant matrix interference for the analysis. Thus, the combination of vortex-assisted MSPD with GC/MS was considered as a novel, rapid, and environmentally friendly quantitative approach for musk samples.

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“…Therefore, the use of sample preparation techniques which imply an in-situ clean-up step is a good approach. In this way, matrix solid-phase dispersion (MSPD) has been proposed for the extraction of different families of cosmetic ingredients such as fragrances, preservatives or dyes [5][6][7].…”

Section: Introductionmentioning

confidence: 99%

Miniaturized Matrix Solid-Phase Dispersion for the Analysis of Ultraviolet Filters and Other Cosmetic Ingredients in Personal Care Products

et al. 2019

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A method based on micro-matrix solid-phase dispersion (μ-MSPD) followed by gas-chromatography tandem mass spectrometry (GC–MS/MS) was developed to analyze UV filters in personal care products. It is the first time that MSPD is employed to extract UV filters from cosmetics samples. This technique provides efficient and low-cost extractions, and allows performing extraction and clean-up in one step, which is one of their main advantages. The amount of sample employed was only 0.1 g and the extraction procedure was performed preparing the sample-sorbent column in a glass Pasteur pipette instead of the classic plastic columns in order to avoid plastizicer contamination. Factors affecting the process such as type of sorbent, and amount and type of elution solvent were studied by a factorial design. The method was validated and extended to other families of cosmetic ingredients such as fragrance allergens, preservatives, plasticizers and synthetic musks, including a total of 78 target analytes. Recovery studies in real sample at several concentration levels were also performed. Finally, the green extraction methodology was applied to the analysis of real cosmetic samples of different nature.

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Comprehensive screening of 63 coloring agents in cosmetics using matrix solid-phase dispersion and ultra-high-performance liquid chromatography coupled with quadrupole-Orbitrap high-resolution mass spectrometry

Cited by 18 publications

References 51 publications

Recent Advances in Sample Preparation for Cosmetics and Personal Care Products Analysis

Recent Advances in Sample Preparation for Cosmetics and Personal Care Products Analysis

Binary Eluent Based Vortex-Assisted Matrix Solid-Phase Dispersion for the Extraction and Determination of Multicomponent from Musk by Gas Chromatography-Mass Spectrometry

Miniaturized Matrix Solid-Phase Dispersion for the Analysis of Ultraviolet Filters and Other Cosmetic Ingredients in Personal Care Products

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