For
the successful cementing operation of petroleum wells, the
design of cement slurry plays a crucial role. Cement slurry must address
the requirements of higher compressive strength; lower fluid loss;
durability; and high-pressure, high-temperature (HPHT) challenges.
A large number of chemical additives in cement slurry affects the
required rheological properties; therefore, the development of multifunctional
additives is desirable. In the present study, this problem has been
addressed with the use of a single polymeric nanocomposite additive
to address multiple requirements. A novel tetrapolymer nanocomposite
(TPN) was synthesized in the laboratory by in situ polymerization
in the presence of zinc oxide nanoparticles. Four monomers, namely
acrylamide, 2-acrylamido-2-methylpropanesulfonic acid, vinyl phosphonic
acid, and N-[3-(dimethylamino)propyl] methacrylamide,
were selected for the in situ polymerization reaction. The synthesized
product was characterized using 1H NMR, FTIR, and TGA techniques.
Laboratory-synthesized TPN was mixed in varying concentrations in
the cement slurry as an additive. The performance of the enhanced
cement slurry was then evaluated by performing compressive strength
analysis and a filtration test using an ultrasonic cement analyzer
and an HPHT filter press, respectively. These experimental analyses
show that the addition of the TPN improved the compressive strength
of the cement slurry and, at the same time, abbreviated the fluid
loss, which is desired for efficient cementing operation. With the
addition of 1.0% by weight of cement (BWOC) of TPN, the compressive
strength increased by ∼136% compared with base cement. Additionally,
this small dosage also reduced HPHT fluid loss by ∼67%. This
experimental investigation shows that the novel TPN additive is capable
of improving the efficacy of oil-well cement slurry at high-temperature
conditions without compromising on thickening time because the additive
also improved the waiting-on-cement time for HPHT conditions.