Conformational landscape of small organosilicon compounds from the combined use of gas electron diffraction, IR and Raman spectroscopies and quantum chemical calculations: diethyldichlorosilane

Abstract

A conformational study of diethyldichlorosilane and the elucidation of the gas-phase molecular structures of its four conformers have been performed using the combined approach of gas-phase electron diffraction and computational techniques. Moreover, the Raman spectrum of the liquid and the IR spectra of the gas and liquid phases have been recorded and thoroughly analyzed on the basis of the scaled quantum-mechanical force field methodology. The results of the vibrational assignment have given spectroscopic evidence of the presence of the different conformers in the samples.

Recent advances in linear and nonlinear Raman spectroscopy. Part V

“…Montejo et al . reported the conformational landscape of small organosilicon compound diethyldichlorosilane from the combined use of gas electron diffraction, IR and Raman spectroscopies and quantum chemical calculations . FT‐IR and FT‐Raman spectra of Me(2‐methyl‐4,6‐dinitrophenylsulfanyl)ethanoate were recorded and analyzed by Panicker et al .…”

Photoluminescence of silicone oil treated by fluorocarbon plasma

“…3. For the silicone oil treated by the C 2 F 6 plasma, except for the Si-CH 3 (1263 cm −1 ) and CH 2 (1412 cm −1 ) peaks, which are also seen in the silicone oil, [16,17] a weak defect peak (D band at 1326 cm −1 ) appears. [18,19] Therefore, the C 2 F 6 plasma treatment leads to the formation of carbon-related defects.…”