CoNi-embedded nitrogen-enriched porous carbon framework for long-life lithium–sulfur batteries

Li, Miaomiao; Feng, Wangjun; Su, Wenxiao; Wang, Xuan

doi:10.1007/s10008-019-04346-x

Cited by 30 publications

(7 citation statements)

References 45 publications

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“…ZIF‐derived Co/N‐co‐doped carbon polyhedra can be combined with other materials, including carbon arrays, [ 132 ] carbon shells, [ 133,134 ] C 60 , [ 135 ] CNFs, [ 136–139 ] other metal nanoparticles, [ 140 ] metal oxides, [ 141,142 ] and metal hydroxides. [ 143 ] For example, Kang et al.…”

Section: Zifs and Their Derivatives To Improve Chalcogen Cathode Utilization In Li–chalcogen Batteriesmentioning

confidence: 99%

Recent Progress on Zeolitic Imidazolate Frameworks and Their Derivatives in Alkali Metal–Chalcogen Batteries

Chen

et al. 2021

Advanced Energy Materials

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The commercialization of high‐energy‐density alkali metal (Li, Na, and K)–chalcogen (S, Se, and Te) batteries (AMCBs) has been primarily hindered by the volume expansion of chalcogen cathodes during repeated charging/discharging cycles, the shuttling effect of intermediates in the electrolytes, and unstable alkali metal anodes. Owing to their unique structural and physicochemical characteristics, including high specific surface areas, self‐doped N atoms, open pore structure, versatile compositions, and favorable chemical stability, zeolitic imidazolate frameworks (ZIFs) and their derivatives have been widely used in different battery components, such as cathodes, anodes, separators, and interlayers, to resolve these issues simultaneously. This review discusses recent advances in ZIFs and their derivatives for cathode construction, anode protection, and interlayer/separator design in AMCBs. The processing methods, structure and morphology engineering, composition tuning, and electrochemical performance of various ZIFs and their derivatives are systematically examined. More importantly, the remaining challenges and future research directions are summarized and discussed. This review is expected to offer new approaches for the rational design of ZIFs and their derivatives for emerging energy storage devices.

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Section: Zifs and Their Derivatives To Improve Chalcogen Cathode Utilization In Li–chalcogen Batteriesmentioning

confidence: 99%

Recent Progress on Zeolitic Imidazolate Frameworks and Their Derivatives in Alkali Metal–Chalcogen Batteries

Chen

et al. 2021

Advanced Energy Materials

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“…Except for one kind of metal atom-decorated carbon material, binary or ternary metal atom-decorated carbon materials have also been reported for enhancing the performances of Li-S batteries (Chen et al, 2019b;Jing et al, 2019;Li et al, 2019c;Ogoke et al, 2019;Zhang et al, 2019a). For instance, Chen's group reported a CoNicarbon nanofiber@carbon fabric heterostructure (CoNi-CNF-CF, Figure 3E) as the interlayer for Li-S batteries.…”

Section: Iron Series Metal Atom (Fe Co Ni)-decorated Carbon Materialsmentioning

confidence: 99%

Metal Atom-Decorated Carbon Nanomaterials for Enhancing Li-S/Se Batteries Performances: A Mini Review

Deng

Ren

2021

Front. Energy Res.

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Lithium-sulfur (Li-S) and lithium-selenium (Li-Se) batteries are both facing the cathode issues of low Coulombic efficiency and unstable cycling stability due to the severe shuttle effect of lithium polysulfides or lithium polyselenides. Simultaneously inhibiting polysulfides/polyselenides dissolution in organic electrolytes and propelling them to conversion via introducing polar, catalytic materials has been proven as an effective strategy to enhance the durability of Li-S and Li-Se batteries. In this mini review, we systematically introduce various metal atom-decorated carbon nanomaterials to determine how to enhance the electrochemical performances of Li-S and Li-Se batteries by inhibiting the polysulfides/polyselenides shuttle phenomenon as well as catalyzing them toward quick redox conversions. We also briefly include the drawbacks and bottlenecks of this kind of material when used in Li-S and Li-Se batteries

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“…1,2 As one of the candidates with most potential in next-generation energy storage, lithium-sulfur batteries (LiSBs) hold great superiority because of their high theoretical energy density of 2600 W h kg À1 , plentiful natural reserves and the environmental friendliness of the sulfur cathode. 3,4 However, there are still certain obstacles with sulfur cathodes that need to be tackled for the commercialization of lithium-sulfur batteries, like the low electrical conductivity of sulfur and Li 2 S, 5 severe volume expansion during charge-discharge cycling 6 and the shuttle effect of soluble intermediate lithium polysulfides (LiPSs) during the cycling process. 7,8 In order to solve the mentioned problems, it is essential to seek a suitable material as the sulfur host, such as porous carbon, [9][10][11] conductive polymers, 12 transition metal oxides/ nitrides, [13][14][15] and MOF-based materials.…”

Section: Introductionmentioning

confidence: 99%

Rational design of a zwitterionic porous organic framework loaded with Co(ii) ions to host sulfur and synergistically boost polysulfide redox kinetics for lithium sulfur batteries

Sun

Yan

et al. 2022

Mater. Adv.

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CoNi-embedded nitrogen-enriched porous carbon framework for long-life lithium–sulfur batteries

Cited by 30 publications

References 45 publications

Recent Progress on Zeolitic Imidazolate Frameworks and Their Derivatives in Alkali Metal–Chalcogen Batteries

Recent Progress on Zeolitic Imidazolate Frameworks and Their Derivatives in Alkali Metal–Chalcogen Batteries

Metal Atom-Decorated Carbon Nanomaterials for Enhancing Li-S/Se Batteries Performances: A Mini Review

Rational design of a zwitterionic porous organic framework loaded with Co(ii) ions to host sulfur and synergistically boost polysulfide redox kinetics for lithium sulfur batteries

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