Constructing ultra-long life and super-rate rechargeable aqueous zinc-ion batteries by integrating Mn doped V6O13 nanoribbons with sulfur-nitrogen modified porous carbon

Wang, X.; Ye, L.; Zou, Yongchun; Zhao, Lijun; Jiang, Qing

doi:10.1016/j.mtener.2020.100593

Cited by 34 publications

(33 citation statements)

References 46 publications

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“…ZIBs. [75][76][77][78][79][80] V 6 O 13 is a mixed valence state oxide of V 4+ and V 5+ which typically crystalizes in the monoclinic crystal system. It has a tunnel-like structure, however unlike other vanadium oxides, V 6 O 13 is composed of alternating single and double VO 6 octahedral layers joined by edge sharing O atoms as depicted in Figure 7a.…”

Section: Vomentioning

confidence: 99%

“…Integration of metal ions (e.g., Mn), and carbon and nitrogen‐containing scaffolds are other methods that have been used to enhance the electrochemical performance of V 6 O 13 ‐based ZIB cathodes. [ 79,80 ]…”

Section: Vanadium‐containing Materialsmentioning

confidence: 99%

“…Integration of metal ions (e.g., Mn), and carbon and nitrogen-containing scaffolds are other methods that have been used to enhance the electrochemical performance of V 6 O 13 -based ZIB cathodes. [79,80] As discussed in Section 3.1, vanadium oxide materials are capable of having many interesting and intricate morphologies. However, these do not always result in the best functionality as a battery cathode.…”

Section: Vomentioning

confidence: 99%

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Vanadium‐Containing Layered Materials as High‐Performance Cathodes for Aqueous Zinc‐Ion Batteries

Lewis

Fernando

Siriwardena

et al. 2021

Adv Materials Technologies

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The world is currently in the midst of a climate crises and many across the globe are competing to find new technologies to create clean, and effective ways of harnessing renewable energy sources. However, this energy needs to be stored and the current systems simply would not last. Zinc‐ion batteries (ZIBs) with vanadium‐containing cathodes are a recently arising technology providing a cheap, safe, and eco‐friendly alternative to the current systems. Vanadium is a material that has long been used for electrochemical systems due to its large range of stable oxidation states. Most common is the vanadium oxide (V2O5) renowned for its open layered framework and manipulatable structure. However, this is not the only vanadium‐containing material that is proposed for use in ZIBs. The vanadium family is comprised of four main sub‐categories under which materials can be classified: vanadium oxides, vanadium phosphates, vanadates, and O2‐free vanadium compounds. This report delves into the specifics of each of these sub‐families to further develop the understanding of their functionality by highlighting their structural and morphological characteristics, aptitude for modification, and the corresponding electrochemical properties. Through this investigation, the application of these materials in ZIB systems is highlighted and future development aims considered.

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Section: Vomentioning

confidence: 99%

Section: Vanadium‐containing Materialsmentioning

confidence: 99%

Section: Vomentioning

confidence: 99%

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Vanadium‐Containing Layered Materials as High‐Performance Cathodes for Aqueous Zinc‐Ion Batteries

Lewis

Fernando

Siriwardena

et al. 2021

Adv Materials Technologies

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“…It was demonstrated that both capacitive and diffusive processes contribute in the total capacity of LiV 3 O 8 electrode. Wang et al [ 179 ] developed a hybrid structure, consisting of Mn‐doped V 6 O 13 nanoribbons and nitrogen–sulfur (N–S)‐modified carbon. Results from the electrochemical tests have shown that this newly designed cathode has excellent stability during long‐term cycling (1000 cycles) and is able to provide 414 and 272 mAh g −1 at current densities of 0.5 and 10 A g −1 , respectively.…”

Section: Electrolyte Modificationsmentioning

confidence: 99%

“…Some examples are V 2 O 5 / graphene, [129] hydrated V 2 O 5 , [132,133] transition metal-intercalated V 2 O 5 (Cu, Ni), [146,154] NH 4 V 4 O 10 , [157] and V 6 O 13 (Mn-doped, hydrated). [174,179] The majority of these materials were prepared by hydrothermal method, which is a simpler method of preparation compared with other techniques shown in Table 2. It appears that hydrated V 2 O 5 and vanadates endure longer cycling at very high current densities than the other materials while maintaining favorable specific capacities.…”

Section: Layered V 2 O 5 -Based Cathodes: Summary and Remarksmentioning

confidence: 99%

Recent Progress in Layered Manganese and Vanadium Oxide Cathodes for Zn‐Ion Batteries

Bensalah

Luna

2021

Energy Tech

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Aqueous zinc‐ion batteries (AZIBs) are promising candidates for grid‐scale energy‐storage systems, which are essential for maintaining and distributing energy generated from various sources. In contrast to current commercial lithium‐ion batteries (LIBs), AZIBs offer advantages such as, but not limited to, high safety, low cost, and fast kinetics. Zn intercalation material serves as the key element for the suitability of Zn‐ion batteries (ZIBs) for grid and stationary applications. Different materials are tested as cathode materials for ZIBs, including manganese oxides and vanadium oxides. MnO2‐ and V2O5‐based cathodes, in particular, seem compatible with ZIBs, with the potential to perform better than existing batteries in the market. Due to the fast and facile (de)intercalation‐type storage mechanism of Zn2+ ions, layered electrode materials generally have a more stable structure during battery charge and discharge cycles. Materials with large interlayer spacing are expected to exhibit good electrochemical performance, thereby favoring hydrated and cation‐intercalated materials in the development of AZIBs cathodes. Herein, an overview is provided on the synthesis, morphology, and electrochemical performance of various MnO2‐ and V2O5‐based cathode materials in AZIB, as well as the challenges that must be overcome to reach the commercialization of AZIBs.

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Zincophobic Electrolyte Achieves Highly Reversible Zinc‐Ion Batteries

Wang

Chen

Wan

et al. 2023

Adv Funct Materials

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Zinc metal batteries show tremendous applications in wide-scale storages still impeded by aqueous electrolytes corrosion and interfacial water splitting reaction. Herein, a zincophobic electrolyte containing succinonitrile (SN) additive is proposed, the SN electrolyte shows a lower affinity for zinc but a stronger affinity for solid-state interphase (SEI). In the SN electrolyte, zinc hydroxide sulfate (ZHS) is more inclined to accumulate horizontally, forming a dense SEI protective layer on the surface of the Zn anode, effectively slowing down the corrosion of Zn and dendrite growth. The zincophobic SN electrolyte enables excellent performance: zinc plating/stripping Coulombic efficiency of 99.71% for an average of 400 cycles; stable cycles in a symmetric cell for 4000 h (0.9% zinc utilization) and 325 h (86.1% zinc utilization). The soft pack battery using limited zinc delivers maximum energy density of 57.0 Wh kg −1 (based on mass loading of cathode materials and anode materials). Such a simple additive strategy provides a theoretical reference for zinc chemistry in a mild electrolyte environment in practical applications.

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Constructing ultra-long life and super-rate rechargeable aqueous zinc-ion batteries by integrating Mn doped V6O13 nanoribbons with sulfur-nitrogen modified porous carbon

Cited by 34 publications

References 46 publications

Vanadium‐Containing Layered Materials as High‐Performance Cathodes for Aqueous Zinc‐Ion Batteries

Vanadium‐Containing Layered Materials as High‐Performance Cathodes for Aqueous Zinc‐Ion Batteries

Recent Progress in Layered Manganese and Vanadium Oxide Cathodes for Zn‐Ion Batteries

Zincophobic Electrolyte Achieves Highly Reversible Zinc‐Ion Batteries

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