Construction of a series of Zn(II) and Cd(II) coordination polymers using a mixed-ligand approach: Structural analysis and photophysical properties

Kirandeep,; Gauri, .; Sharma, Ananay; Guda, Ramu; Kumar, Praveen; Kataria, Ramesh; Husain, Ahmad; Kumar, Girijesh

doi:10.1016/j.poly.2019.02.048

Cited by 10 publications

(1 citation statement)

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“…3) with point symbol {4^4.6^10.8} as suggested by topological analysis 32 where each of the Cu1 atom act as the 6-connecting node while the aqua-ligated Cu2 serve as a two-way connector. The whole network of 2 can be best simplified as 4-connected unimodal dia net 33 (Fig. 4) with sqc6 topology with point symbol {6^6} as suggested by topological analysis 32 where each of the Na atom act as the 4-connecting node while the Ni-paddlewheel serves as a two-way connector.…”

Section: Synthesismentioning

confidence: 99%

Synthetic, spectral, structural and catalytic activities of 3-D metal format/acetate framework materials for CO₂ conversion

et al. 2023

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Section: Synthesismentioning

confidence: 99%

Synthetic, spectral, structural and catalytic activities of 3-D metal format/acetate framework materials for CO₂ conversion

et al. 2023

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Preparation and properties of uncommon Cd‐Mn carboxylate complexes—per se and as precursors for CdMn₂O₄‐based ceramics

Гавриков

Belova

Koroteev

et al. 2021

Applied Organom Chemis

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Carboxycymantrene CymCOOH (Cym = (η5‐C5H4)Mn (CO)3) was applied to assemble a series of uncommon Cd‐Mn carboxylate complexes comprising 1D‐polynuclear [Cd (OOCCym)(acac)]n (1) as well as oligonuclear species, [Cd2(OOCCym)4(EtOH)4)] (2), [Cd (OOCCym)2(bpy)(H2O] (3, bpy = 2,2′‐bipyridine) and [Cd (OOCCym)2(phen)2]·EtOH (4, phen = 1,10‐phenantroline). Compound 2 was found to be a product of irreversible SCSC transition from [Cd2(OOCCym)4(EtOH)3(H2O)]·EtOH (2_100K) initially formed in corresponding syntheses. This transition is accompanied by two‐fold decrease in cell volume and increase in cell symmetry. Recrystallyzation of 2–4 from common organic solvents affects the nuclearity of products (in case of 2 and 3) or subtly alters the structure of [Cd (OOCCym)2(phen)2] units (4). The optimal Cd to Mn ratio inspired studying solid‐state thermal decomposition of 2–4 as a route to CdMn2O4‐based ceramics. As a result, oxide samples with a predominance of tetragonal (Cd1‐xMnx)Mn2O4 spinel have been prepared and characterized by powder XRD, SEM, EDX, and IR revealing the interplay between the preparation technique and the features of morphology and composition. The retaining of Cd to Mn ratio upon recrystallyzation of 2–4 implies possibility of further elaboration of CdMn2O4‐based materials in various morphologies (polycrystalline ones, films, etc.). Notably, 2–4 is also the first series of related heterometallic Cd‐Mn complexes being studied as individual precursors for CdMn2O4‐based oxide systems.

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Zinc(II)-Coordination Polymers Based on Isomeric Azo-Containing Anionic and Neutral Linkers

Arıcı

Yeşılel

2022

J Inorg Organomet Polym

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Construction of a series of Zn(II) and Cd(II) coordination polymers using a mixed-ligand approach: Structural analysis and photophysical properties

Cited by 10 publications

References 50 publications

Synthetic, spectral, structural and catalytic activities of 3-D metal format/acetate framework materials for CO₂ conversion

Synthetic, spectral, structural and catalytic activities of 3-D metal format/acetate framework materials for CO₂ conversion

Preparation and properties of uncommon Cd‐Mn carboxylate complexes—per se and as precursors for CdMn₂O₄‐based ceramics

Zinc(II)-Coordination Polymers Based on Isomeric Azo-Containing Anionic and Neutral Linkers

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Construction of a series of Zn(II) and Cd(II) coordination polymers using a mixed-ligand approach: Structural analysis and photophysical properties

Cited by 10 publications

References 50 publications

Synthetic, spectral, structural and catalytic activities of 3-D metal format/acetate framework materials for CO2 conversion

Synthetic, spectral, structural and catalytic activities of 3-D metal format/acetate framework materials for CO2 conversion

Preparation and properties of uncommon Cd‐Mn carboxylate complexes—per se and as precursors for CdMn2O4‐based ceramics

Zinc(II)-Coordination Polymers Based on Isomeric Azo-Containing Anionic and Neutral Linkers

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About

Synthetic, spectral, structural and catalytic activities of 3-D metal format/acetate framework materials for CO₂ conversion

Synthetic, spectral, structural and catalytic activities of 3-D metal format/acetate framework materials for CO₂ conversion

Preparation and properties of uncommon Cd‐Mn carboxylate complexes—per se and as precursors for CdMn₂O₄‐based ceramics