With the globalization of the world’s economy, culture, science and technology, and the increasing frequency of international cooperation and exchanges, English will play an increasingly important role. For non-English majors in Chinese colleges and universities, college English is a public compulsory basic course, which plays a very important role in expanding students’ knowledge, improving foreign language cultural literacy and comprehensive language use ability. An important part of college English classroom teaching is teaching evaluation, which not only helps teachers obtain teaching feedback information, improve teaching management, and ensure teaching quality, but also effectively helps students adjust learning strategies, improve learning methods, and improve learning efficiency. The English classroom teaching quality evaluation could be deemed as a classic multiple attribute group decision making (MAGDM) problem. In this paper, as a useful outranking approach, the extended QUALIFLEX method is utilized to address some MAGDM issues by using picture 2-tuple linguistic sets (P2TLSs). In addition, integrating the QUALIFLEX method with P2TLSs, the extended QUALIFLEX method with P2TLNs is constructed and all calculating procedures are simply depicted. Eventually, an empirical application of English classroom teaching quality evaluation has been offered to demonstrate this novel method.