In this paper, a non-permutation variant of the Flow Shop Scheduling Problem with Time Couplings and makespan minimization is considered. Time couplings are defined as machine minimum and maximum idle time allowed. The problem is inspired by the concreting process encountered in industry. The mathematical model of the problem and solution graph representation are presented. Several problem properties are formulated, including the time complexity of the goal function computation and block elimination property. Three solving methods, an exact Branch and Bound algorithm, the Tabu Search metaheuristic, and a baseline Genetic Algorithm metaheuristic, are proposed. Experiments using Taillard-based problem instances are performed. Results show that, for the Tabu Search method, the neighborhood based on the proposed block property outperforms other neighborhoods and the Genetic Algorithm under the same time limit. Moreover, the Tabu Search method provided high quality solutions, with the gap to the optimal solution for the smaller instances not exceeding 2.3%.