Technology Computer-Aided Design is widely used for the development and optimization of advanced device formation. Ion implantation and thermal annealing are the main focus of dopant profile simulation for process technologies. In this paper, we review the current continuum modeling capabilities and calibration for ion implantation and thermal processes, including Monte Carlo ion implantation, coimplantation, amorphization, recrystallization, damage evolution, and dopant diffusion and activation. In addition, modeling of alternative doping techniques such as thermal implantation, plasma doping, and melt laser annealing will be addressed. Continuum front-end process simulation of Si-based devices including advanced CMOS, memory, power, and optoelectronic devices is considered to be mature. With the introduction of new channel materials, the models and calibration of alternative materials such as SiGe, Ge, and III-V are also required and their current status is discussed.