PACS : 73.40.Kp; 73.61.Ey; 81.15.Gh Crack-free Al x Ga 1--x N films with an Al mole fraction of up to 37% were successfuly grown on a sapphire substrate by introducing a 10 nm-thick low-temperature (LT) Al x Ga 1--x N interlayer. Three AlGaN layer structures were tested for application to solar-blind UV photodetectors. Among them, Schottky diodes with a Pt/0.5 mm thick Al 0.33 Ga 0.67 N/10 nm thick LT-Al 0.33 Ga 0.67 N interlayer/ 2 mm thick n + -GaN layer exhibited the best behavior with a reverse leakage current of 9 nA at À5 V, UV-visible extinction ratio of $10 4 , and responsivity of 0.15 A/W at 280 nm.