The annual global output of denim exceeds a staggering
9 billion
meters, valued at over $25 billion. The conventional production relies
on sodium dithionite for indigo dye reduction, a costly process that
also generates environmentally harmful wastewater with sulfite and
sulfate ions. Addressing these issues, we present an eco-friendly,
cost-effective electrochemical reduction approach using a novel molybdenum
disulfide (MoS2) molecule–proton dual adsorption
system for the electrocatalytic hydrogenation (ECH) of indigo dye.
This system facilitates a phase shift from 2H to 1T in MoS2 by intercalating organic amine cations, enhancing the coadsorption
of active hydrogen and indigo molecules, thereby boosting the ECH
activity. The dimethylamine-cation intercalated MoS2 electrode
material (MoS2-DMA-CF) achieves over 95% dye reduction
efficiency and more than 75% faradaic efficiency in ECH, surpassing
traditional methods with a 25% increase in K/S value, improved color fastness, and less than 5% color
variation after 10 cycles. Additionally, this method reduces energy
consumption by 92.424% and dyeing costs by 90.416%, with the dyeing
wastewater exhibiting excellent biodegradability, offering substantial
environmental benefits. This innovative approach not only yields significant
cost savings but is also highly scalable, providing a sustainable
solution for denim fabrication.