Controlled crystallisation of porous crystals of luminescent platinum(<scp>ii</scp>) complexes by electronic tuning of ancillary ligands

Mochizuki, Takanari; Yoshida, Masaki; Kobayashi, Atsushi; Kato, Masako

doi:10.1039/d4dt00713a

Dalton Trans.

2024

DOI: 10.1039/d4dt00713a

|View full text |Cite

Controlled crystallisation of porous crystals of luminescent platinum(ii) complexes by electronic tuning of ancillary ligands

Takanari Mochizuki,

Masaki Yoshida,

Atsushi Kobayashi

et al.

Abstract: Porous molecular crystals (PMCs) have gained significant importance as next-generation functional porous materials. However, the selective crystallisation of the PMC phase remains a challenge. Herein, we have systematically controlled the...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 92 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Circularly Polarized Phosphorescence Properties of Binuclear Cyclometalated Platinum(II) Complexes Bearing Axially Chiral Schiff-Base Ligands

Ikeshita,

Shimizu,

Watanabe

et al. 2024

Inorg. Chem.

View full text Add to dashboard Cite

The synthesis, structure, and circularly polarized phosphorescence (CPP) properties of axially chiral cyclometalated binuclear platinum(II) complexes were described. A series of optically pure binuclear platinum(II) complexes were synthesized in five steps from commercially available (R)-or (S)-1,1′-bi-2naphthol (BINOL) as starting materials. Their three-dimensional molecular structures and square-planar coordination geometries were elucidated from X-ray diffraction and 2D NMR analysis. The complexes were found to exhibit red-to near-infrared photoluminescence in solution and in the solid state. Furthermore, dilute DMSO solutions of the enantiopure samples showed red CPP with relatively high luminescence dissymmetry factor (g lum ) values. Density functional theory (DFT) calculations were conducted to examine their three-dimensional molecular conformations and photophysical properties.

show abstract

Circularly Polarized Phosphorescence Properties of Binuclear Cyclometalated Platinum(II) Complexes Bearing Axially Chiral Schiff-Base Ligands

Ikeshita,

Shimizu,

Watanabe

et al. 2024

Inorg. Chem.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Controlled crystallisation of porous crystals of luminescent platinum(ii) complexes by electronic tuning of ancillary ligands

Abstract: Porous molecular crystals (PMCs) have gained significant importance as next-generation functional porous materials. However, the selective crystallisation of the PMC phase remains a challenge. Herein, we have systematically controlled the...

Cited by 1 publication

References 92 publications

Circularly Polarized Phosphorescence Properties of Binuclear Cyclometalated Platinum(II) Complexes Bearing Axially Chiral Schiff-Base Ligands

Circularly Polarized Phosphorescence Properties of Binuclear Cyclometalated Platinum(II) Complexes Bearing Axially Chiral Schiff-Base Ligands

Contact Info

Product

Resources

About