In this study, the sulfurized (BiO) 2 CO 3 heterostructures were synthesized using a facile liquid-phase sulfurization strategy and characterized by XRD, SEM, FT-IR, XPS, UV-Vis DRS and PL techniques. It is found that sulfurization shifts slightly XRD diffraction peaks toward to lower Bragg angle, enhances significantly the optical absorption and reduces the recombination of photogenerated electrons and holes. Based on the experimental results, it is considered that novel Bi 2 S 3 /(BiO) 2 CO 3 heterostructures with S doping (oxygen atoms substituted by sulfur) were successfully constructed. The as-obtained photocatalysts showed excellent photocatalytic activity for degradation of reactive brilliant blue (KN-R), as compared with that of pure (BiO) 2 CO 3 under sunlight irradiation. The enhanced photocatalytic performance may be ascribed to the role of Bi 2 S 3 / (BiO) 2 CO 3 heterostructure and S doping, which causes high absorption efficiency of light and efficient separation of photoinduced carriers in sulfurized (BiO) 2 CO 3 .