2004
DOI: 10.1063/1.1664015
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Controlling energy dissipation and stability of micromechanical silicon resonators with self-assembled monolayers

Abstract: Self-assembled alkyl monolayers that are directly tethered to the silicon surface with a Si–C bond suppress mechanical energy dissipation in megahertz-range micromechanical silicon oscillators as compared to the more common silicon oxide coating. Although not as low loss as freshly prepared H-terminated surfaces, Si–C tethered monolayers are more stable with time. Alkyl monolayers derived from chlorosilanes have much poorer mechanical performance. Both types of monolayers suppress adsorption.

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Cited by 25 publications
(32 citation statements)
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“…In some systems, particularly for small Si oscillators, losses due to surface dissipation may dominate the total measured dissipation [18,21]. The surface may be a source of atomic defects leading to high defect-related dissipation, or, as is the case with Si, the surface may be covered with a lossy material, such as amorphous SiO 2 , that causes a decrease in quality factor as it grows on the surface [22]. For a cantilever geometry, the quality factor of the surface, Q surf , covered with a lossy material of thickness, d, elastic modulus E s , and characteristic dissipation = 1/Q s is given by where t is the oscillator thickness and E is the Young's modulus for the oscillator material, not including the surface.…”
Section: Extrinsic Internal Dissipationmentioning
confidence: 99%
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“…In some systems, particularly for small Si oscillators, losses due to surface dissipation may dominate the total measured dissipation [18,21]. The surface may be a source of atomic defects leading to high defect-related dissipation, or, as is the case with Si, the surface may be covered with a lossy material, such as amorphous SiO 2 , that causes a decrease in quality factor as it grows on the surface [22]. For a cantilever geometry, the quality factor of the surface, Q surf , covered with a lossy material of thickness, d, elastic modulus E s , and characteristic dissipation = 1/Q s is given by where t is the oscillator thickness and E is the Young's modulus for the oscillator material, not including the surface.…”
Section: Extrinsic Internal Dissipationmentioning
confidence: 99%
“…Several authors have reported graphitization of DLC films and used this to write conducting lines [16], remove hydrogen [20], and create patterned structures. Others have worked above the ablation threshold to produce patterned structures [17,[22][23][24]. There have been several reports of amorphous-to-crystalline phase transformations in laser-annealed carbon [26] and hydrogenated DLC [15,18,25] thin films.…”
Section: Introductionmentioning
confidence: 99%
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“…Water adsorbing is believed to be the main cause of drift in unpackaged components. Surface treatment of the unpackaged torsional resonators reduces the drift to less than 100 ppm/week [11]. Ceramic vacuum encapsulated BAW resonators have been demonstrated yield drift less than 1 ppm in 40 days [12].…”
Section: Introductionmentioning
confidence: 99%
“…Unpackaged torsional mode resonators show drift of more than 100 ppm/day [11]. Unpackaged BAW resonators demonstrate stability better than 50 ppm/week [12].…”
Section: Introductionmentioning
confidence: 99%