To improve the heat and mass transfer performances of falling films and develop a new type of falling film evaporator, the characteristics of falling film evaporation and sensible heat and mass transfer in four different sizes of converging-diverging (CD) tubes were experimentally explored in this study. By analyzing the relationship between the heat transfer coefficient and the falling film flow rate, it was found that the CD tube is suitable for falling film evaporation and sensible heating with a large Reynolds number. For different sizes of tubes, the key factor affecting the heat transfer in falling film evaporation and sensible heating is the height of the ribs. At the same rib height and rib pitch, the longer the converging segment of the CD tube, the better the heat transfer performance. According to the comparative analysis of the evaporation and sensible heating heat transfer performances inside the four CD tubes, the CD tube 3# is best. The evaporation heat transfer coefficient (at Reynolds number of liquid films of 2356), evaporation mass transfer rate (at the perimeter flow rate of liquid films is 0.173 kgm-1 s-1), and sensible heating heat transfer coefficient (at Reynolds number of liquid films of 1635) of CD tube 3# are 62%, 38% and 63% higher than that of the smooth tube, respectively. For the same CD tube, the evaporation heat transfer coefficient is larger than the sensible heating heat transfer coefficient, but both increases as the flow rate increases. The heat transfer correlations of falling film evaporation and sensible heating in the experimental range were obtained through data fitting. It will provide a useful reference for future engineering design and industrial applications.