1944
DOI: 10.1021/cr60111a002
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Conversion of Hydrocarbons into Butadiene.

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Cited by 4 publications
(3 citation statements)
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“…Ostromyslenskii considered the conversion to involve probably dehydration to 2-butene, dehydrogenation to cyclobutene, and isomerization of the latter ( 136 There are several reasons why butadiene should be formed from diethyl ether over aluminum at 300-600°C. First, ethanol and ethene, which are respectively expected and actual products, are each directly convertible into butadiene under similar conditions (21,23,72). Ethanal, another product, upon dimerization to 3-hydroxybutanal, with or without dehydration to 2-butenal, would be a further source of alkadiene.…”
Section: Oxide Derivatives Of Hydrocarbonsmentioning
confidence: 99%
See 1 more Smart Citation
“…Ostromyslenskii considered the conversion to involve probably dehydration to 2-butene, dehydrogenation to cyclobutene, and isomerization of the latter ( 136 There are several reasons why butadiene should be formed from diethyl ether over aluminum at 300-600°C. First, ethanol and ethene, which are respectively expected and actual products, are each directly convertible into butadiene under similar conditions (21,23,72). Ethanal, another product, upon dimerization to 3-hydroxybutanal, with or without dehydration to 2-butenal, would be a further source of alkadiene.…”
Section: Oxide Derivatives Of Hydrocarbonsmentioning
confidence: 99%
“…In this study butadiene means the 1,3or conjugated isomer. A previous study considers the production of butadiene from hydrocarbons (21).…”
mentioning
confidence: 99%
“…In a paper on the dissociation of carbon bonds, Schmidt (74) drew attention to the double-bond rule-"the double bond between two carbon atoms strengthens the following single carbon bond and weakens the next following"-and cited seven instances. This statement is conveniently known as Schmidt's double-bond rule (52).…”
Section: H C C6h6mentioning
confidence: 99%