Copolymerization of Pyrrole and Thienyl end Capped Poly(dimethylsiloxane) by Iron (III) Chloride

Gençoğlu, Duygu; Güvel, Esin Ateş; Ülkü, Görkem; Kızılcan, Nilgün; Köken, Nesrin

doi:10.1016/j.sbspro.2015.06.243

Cited by 4 publications

(2 citation statements)

References 26 publications

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“…Consequently, the formation of polypyrrole has the main chain through the 2-5 coupling [37,38]. The ANT homopolymer is essentially characterized by the main bands observed at (469, 710, 770, 758, 1238, 1210, 1382, 1564.7, 1623, and 3042).…”

Section: Infrared Absorptionmentioning

confidence: 99%

New Π-Conjugated Oligomers Based on Pyrrole and Anthracene for Applications in Organic Electronics Devices

Kacimi

Chemek²,

Bourass³

et al. 2022

SSRN Journal

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Section: Infrared Absorptionmentioning

confidence: 99%

New Π-Conjugated Oligomers Based on Pyrrole and Anthracene for Applications in Organic Electronics Devices

Kacimi

Chemek²,

Bourass³

et al. 2022

SSRN Journal

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“…Indeed, the redox grafting part can occur at RT when post polymerization (to induce block copolymerization) can be triggered by another stimulus (e.g. thermal for labile azo compounds) [296][297][298]. Graft polymerization of surfaces was also proposed via redox cationic (silver salt/Fe(0) surface) polymerization of activated epoxides (EPOX).…”

Section: Redox Graft Polymerization and Block Copolymerizationmentioning

confidence: 99%

Redox two-component initiated free radical and cationic polymerizations: Concepts, reactions and applications

Garra

Dietlin

Morlet‐Savary

et al. 2019

Progress in Polymer Science

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Redox polymerizations are of huge importance throughout academic and industrial polymer science. Many authors propose the reaction of reducing (Red) and oxidizing (Ox) agents to accelerate/initiate radical or cationic polymerizations. As a result of activation energies typically below 80 kJ/mol, such reactions can occur under mild conditions, e.g., at room temperature, with reduced energy consumptions and robust in applications, such as the fabrication of composites. However, a clear definition of redox polymerization can only be found in reviews dealing with redox free radical polymerizations (FRP) published twenty years ago (or more). Therefore, a fresh and broader update is provided here for more recent work. The concepts involved when the "Red" and "Ox" agents constituting the redox initiating system are mixed under mild conditions are presented, followed by a discussion of the redox FRP initiating systems in bulk. Initiating systems dealing with the redox cationic polymerization (CP) are reviewed, and parallels between conventional FRP/CP and controlled polymerizations, in which redox systems are used, is provided. Many redox agents are useful in both modes. Finally, dual-cure (redox/photochemical; redox dual FRP/CP) systems is presented and selected applications are reviewed. Altogether, the state of the art for redox two-component polymerizations is provided, along with some perspectives.

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Synthesis, experimental and theoretical characterization of a new copolymer bearing pyrrole and anthracene units

Kacimi

Chemek²,

Bouchikhi³

et al. 2022

Journal of Photochemistry and Photobiology A: Chemistry

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Copolymerization of Pyrrole and Thienyl end Capped Poly(dimethylsiloxane) by Iron (III) Chloride

Cited by 4 publications

References 26 publications

New Π-Conjugated Oligomers Based on Pyrrole and Anthracene for Applications in Organic Electronics Devices

New Π-Conjugated Oligomers Based on Pyrrole and Anthracene for Applications in Organic Electronics Devices

Redox two-component initiated free radical and cationic polymerizations: Concepts, reactions and applications

Synthesis, experimental and theoretical characterization of a new copolymer bearing pyrrole and anthracene units

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