Copper(II) complex of 3-cinnamalideneacetylacetone: Synthesis and characterisation

Veeraraj, A.; Sami, Ponnusamy; Raman, Natarajan

doi:10.1007/bf02709284

Cited by 14 publications

(3 citation statements)

References 13 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…At the temperature range 185-200°C the thermogram curve of Fe (III) complex shows weight loss 7.40% (calcd. 7.78%) and at 190°C it shows keen endotherm which distinctly designate removal of two coordinated water molecules 37 . The anhydrous complex revealed a single step decomposition with 70% mass loss and a broad endothermic peak in the DTA at the temperature range from 210°C to 820°C.…”

Section: Molarmentioning

confidence: 95%

Untitled

2023

IJPSR

View full text Add to dashboard Cite

Consistently the preparation of transition metal complexes of βdiketones has been (and it still is) an area of the highest interest for inorganic and organic chemists, as can be inferred considering the quantity and diversity of research developed in this field. 1,3-Diketones are wide range of valuable molecules including several types of carbocycles and heterocycles hence have high interest. In fact, excessive amount of therapeutical uses are associated with these 1,3-Diketone compounds. The present work is based mainly on the ultrasound irradiation synthesis of various β-diketone ligands and their Fe (III) complexes. At ambient temperature, the clinically active and functionalized various β-diketones has been synthesized from Baker-Venkataraman transformation and its Fe (III) complexes has been prepared and characterized by physical, spectral and analytical data. The different spectroscopic analysis like Mass, 1 H-NMR, 13 C-NMR, IR, UV and elemental analysis were done. The functionalized beta-diketones showed a certain behaviour and behaved as bidentate ligand and co-ordinate with the transition metal atom through betadiketo system. The complexes have general formula [ML 2 ]. The biological activities like antibacterial and antifungal were performed for the synthesized compounds. The biological screening data indicated that the transition metal complexes are more potent antibacterial, antifungal and antioxidant agents than the parent functionalized beta diketones against different species of bacteria and fungi. This constitutes a new group of compounds. The thermal stability of the newly synthesized metal complexes has been studied. INTRODUCTION:For almost a century the chemistry of 1,3-diketones has attracted the attention of scientists. Diketones are the key intermediates for the synthesis of heterocycles such as isoxazole 1 , flavones 2 , pyrimidine 3 , triazole 4 , pyrazole [5] and benzodiazepines 6 . β-diketone for eg. Anabena β-diketone hydrolase have some QUICK RESPONSE CODE

show abstract

Section: Molarmentioning

confidence: 95%

Untitled

2023

IJPSR

View full text Add to dashboard Cite

show abstract

“…The IR spectral data of the ligands (L1 and L2) and their metal(II) complexes are listed in Table 2. The spectral bands for ligands (L1 and L2) appears in the range of 1695, 1699 cm −1 and 1600, 1629 cm −1 are assigned to the stretching vibrations of ν(C=O) and ν(C=C) [22,23] respectively. The shifting of the same bands to lower frequency in all the metal(II) complexes implies the coordination of carbonyl group to the central metal ion.…”

Section: Ir Spectramentioning

confidence: 99%

Spectral, NLO, Fluorescence, and Biological Activity of Knoevenagel Condensate of β-Diketone Ligands and Their Metal(II) Complexes

Sumathi¹,

Anitha²,

Tharmaraj³

et al. 2011

International Journal of Inorganic Chemistry

View full text Add to dashboard Cite

Transition metal complexes of various acetylacetone-based ligands of the type ML (where M= Cu(II), Ni(II), Co(II); L= 3-(aryl)-pentane-2,4-dione) have been synthesized. The structural features have been derived from their elemental analysis, magnetic susceptibility, molar conductance, IR, UV-Vis, H1NMR, mass and ESR spectral studies. Conductivity measurements reveal that all the complexes are nonelectrolytic in nature. Spectroscopic and other analytical data of the complexes suggest square planar geometry for copper(II), cobalt(II), and nickel(II) complexes of 3-(3-phenylallylidene)pentane-2,4-dione and octahedral geometry for other metal(II) complexes. The redox behaviors of the copper(II) complexes have been studied by cyclic voltammetry. The free ligands and their metal complexes have been screened for their in vitro biological activities against bacteria and fungus. The metal(II) complexes are found to possess increased activities compared to those of the free ligands. All synthesized compounds may serve as potential photoactive materials as indicated from their characteristic fluorescence properties. The second harmonic generation (SHG) efficiency of the ligands was found to have considerable effect compared to that of urea and KDP.

show abstract

“…The bdiketone 3-salicylidene-2, 4-pentanediones and related compounds have been used successfully as proper chelating agents for a series of metal ions (Mishra et al, 1991;Wang et al, 1997). Knoevenagel condensates of substituted benzylidenes with active methylene compounds have been performed efficiently using ultra stable Zeolite as heterogeneous catalyst (Veeraraj et al, 2000). The chelation behavior of a series of dicarbonyl towards some metal ions has been reported (Krishnankutty and Venugopalan, 2001).…”

Section: Introductionmentioning

confidence: 99%

Synthesis of Polyfunctional Organic Systems Containing 1-Acyl/Aroyl-anilido-butadienes and their uses as Photochemical Probes and Chelating Agents for Removal of Bismuth (III) from Industrial Wastewater

Makki¹,

Abdel‐Rahman²,

El-Shahawi³

2010

JBABM

View full text Add to dashboard Cite

The present article reports the synthesis of a series of some new 1-acyl/ benzoyl-1-anilido-4-methyl /aryl-1, 3-butadiene derivatives (II-IV) by warming primary heteroamines and/ or sulfa drugs with pre heated ethyl acetoacetate and / or ethyl benzoylacetate in dry conditions followed by condensation with unsaturated aromatic aldehydes in boiling ethanol-piperidine. The chemical structures of the compounds were characterized via their elemental analysis and spectroscopic measurements (UV Vis., IR, 1 HNMR). Some of the compounds (IIId, e, f, IV d, e,f) were tested as antimicrobial and photochemical probe agents. Compound IVa was physically loaded onto polyurethane solid sorbent and successfully used for the removal and / or pre concentration of bismuth (III) from industrial wastewater. The voltammetric behavior of the two compounds IIa and IVa in N, N-dimethylformamide was investigated.

show abstract

Copper(II) complex of 3-cinnamalideneacetylacetone: Synthesis and characterisation

Cited by 14 publications

References 13 publications

Untitled

Untitled

Spectral, NLO, Fluorescence, and Biological Activity of Knoevenagel Condensate of β-Diketone Ligands and Their Metal(II) Complexes

Synthesis of Polyfunctional Organic Systems Containing 1-Acyl/Aroyl-anilido-butadienes and their uses as Photochemical Probes and Chelating Agents for Removal of Bismuth (III) from Industrial Wastewater

Contact Info

Product

Resources

About