1956
DOI: 10.1021/ja01593a033
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Correlation of Solvolysis Rates. III.1 t-Butyl Chloride in a Wide Range of Solvent Mixtures2

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Cited by 361 publications
(128 citation statements)
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“…In treating the fluorocarbons, we have set 6 = 0 in our correlation using eq. [15]. To improve the fit, we would suggest IT* = -0.09 instead of -0.33.…”
Section: Comparison With Eq [I]mentioning
confidence: 99%
“…In treating the fluorocarbons, we have set 6 = 0 in our correlation using eq. [15]. To improve the fit, we would suggest IT* = -0.09 instead of -0.33.…”
Section: Comparison With Eq [I]mentioning
confidence: 99%
“…Fainberg ancl \Viilstein (14) have shown that the steps indicated in ieaction [IV] need t o be coilsidered in a reaction which proceeds by a dissociatioil nzechanisin. These steps are intended to represent the sequence of events in which the tiiro ionic fragments of the reaction first become separate identities in intimate coiltact (i~lternal ion pair (14)), then ions in contact but each ion \vitIl an indepeildeilt solvation sheath, and finally separated and independent ions.…”
Section: Ici~zet Ic Dfeaszwementsmentioning
confidence: 99%
“…A rate increase at higher NaOAc concentrations could have been anticipated as a result of a normal salt effect (18). Alternatively, if products were formed from the free, dissociation triphenylvinyl cation, a greater extent of product formation with a consequent decrease in external ion return and an increase in rate would be expected at higher salt concentrations.…”
Section: Resultsmentioning
confidence: 99%