The aim of this study was the synthesis of three different epoxy compounds based on naphthalene-2,7-diol (2,7-NAF.EP, 2,7-NAF.WEP, 2,7-NAF.P.EP) and then their cross-linking by triethylenetetramine (TETA). All epoxides were prepared by the reaction of naphthalene-2,7-diol with epichlorohydrin but under different conditions and with other catalysts. The structures of the obtained compounds before and after the cross-linking reactions were confirmed by the attenuated total reflectance Fourier transform infrared spectroscopy (ATR/FT-IR). The ATR/FT-IR spectra of cross-linked compounds show disappearance of the CO -C bands (about 915 cm-1) derived from the epoxy groups. DSC and TG/DTG measurements indicated that the obtained materials possess good thermal resistance; they are stable up to about 250°C. The hardness of the cross-linked products was determined using the Shore D method. The highest value of hardness was obtained for the 2,7-NAF.EP-POL. Additionally, the UV-Vis absorption spectra of the obtained polymers were registered and evaluated.