Corrosion resistance of 13wt.% Cr martensitic stainless steels: Additively manufactured CX versus wrought Ni-containing AISI 420

Shahriari, A.; Ghaffari, Mahya; Khaksar, Ladan; Nasiri, Ali; Hadadzadeh, Amir; Amirkhiz, Babak Shalchi; Mohammadi, Mohsen

doi:10.1016/j.corsci.2021.109362

Cited by 61 publications

(10 citation statements)

References 45 publications

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“…That indicates that the V 2 O 5 possesses a better corrosion resistance, and the V 2 O 5 /Ca 0.17 V 2 O 5 has a higher charge transfer rate. , Meanwhile, the corrosion potential ( E corr ) can represent thermodynamic tendency to oxidation or passivation. , The E corr of V 2 O 5 /Ca 0.17 V 2 O 5 is −0.022 V, which is higher than that of V 2 O 5 (−0.047 V). The higher E corr means the V 2 O 5 /Ca 0.17 V 2 O 5 film electrode has a lower thermodynamic tendency to oxidation or passivation, which can be ascribed to the different chemical composition and microstructure. , To understand the electrode reaction kinetics of films, EIS measurements are characterized in Figure b. The Nyquist plots consist of an intercept at a high frequency and a sloping line at a low frequency.…”

Section: Resultsmentioning

confidence: 99%

“…The higher E corr means the V 2 O 5 /Ca 0.17 V 2 O 5 film electrode has a lower thermodynamic tendency to oxidation or passivation, which can be ascribed to the different chemical composition and microstructure. 63,64 To understand the electrode reaction kinetics of films, EIS measurements are characterized in Figure 8b. The Nyquist plots consist of an intercept at a high frequency and a sloping line at a low frequency.…”

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confidence: 99%

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Synergistic Effect of Composite V₂O₅/Ca_0.17V₂O₅ Film Electrodes as High-Performance Cathodes of SIBs

Liu

et al. 2023

Energy Fuels

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The V 2 O 5 /Ca 0.17 V 2 O 5 film electrodes on indiumdoped tin oxide (ITO) conductive glasses were synthesized by a low-temperature liquid-phase deposition method and thermal treatment. The deposited film electrodes were directly used as cathodes for sodium-ion batteries without additional media. X-ray diffraction and high-resolution transmission electron microscopy results demonstrated that V 2 O 5 /Ca 0.17 V 2 O 5 films were successfully formed. The ions diffusion, electrode reaction kinetics, capacity, and cyclic performance were revealed by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge measurements. The V 2 O 5 /Ca 0.17 V 2 O 5 film delivered a discharge capacity of 148.465 mAh m −2 at 1 C rate, which was larger than 100.086 mAh m −2 of the pure V 2 O 5 film. Moreover, the V 2 O 5 /Ca 0.17 V 2 O 5 film exhibited an initial discharge capacity of 144.712 mAh m −2 (90.11% retained after 100 cycles) at a 1 C rate and 112.525 mAh m −2 (103.91% retained after 100 cycles) at a 2 C rate. Encouragingly, the rate performance was worthy of mention, which indicated a good reversibility. The impressive electrochemical ability could be attributed to the synergistic effect of two phases. The ex-situ X-ray diffraction and X-ray photoelectron spectroscopy results proved that the Ca 0.17 V 2 O 5 supported the stability of the structure, and the V 2 O 5 phase acted as a host material for ions insertion/extraction. This work may provide a promising strategy for developing high-performance electrode materials.

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Section: Resultsmentioning

confidence: 99%

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confidence: 99%

Synergistic Effect of Composite V₂O₅/Ca_0.17V₂O₅ Film Electrodes as High-Performance Cathodes of SIBs

Liu

et al. 2023

Energy Fuels

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Section: Resultsmentioning

confidence: 99%

“…[19,20] The presence of inductive effects is usually attributed to the incomplete dissolution of the passive film adjacent to some surface heterogeneities, such as grain boundaries or interfaces of different phases, subsequently leading to an inductive behavior. [21] As depicted in Figure 4, the smallest diameter is observed from the plot of Sample 1#, indicating the weakest resistance to the corrosive medium. Thereafter, the diameter of the capacitance arc extends with the increase of RE content.…”

Section: Electrochemistry Impedance Spectroscopymentioning

confidence: 86%

Corrosion behavior and kinetics model of rare earth low‐alloy steel in a soil simulation solution

Zhang

Dong

Ding

et al. 2022

Materials & Corrosion

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The corrosion behavior of rare earth (RE) low-alloy steel in soil simulation solution was investigated by immersion test, electrochemical experiment, scanning electron microscopy, and X-ray diffraction, compared with Q450 weathering steel. The kinetics model of all steels in soil simulation solution was established. The pitting corrosion mechanism of nonmetallic and RE inclusions was discussed. The results revealed that the RE improved the corrosion resistance of low-alloy steel by modifying inclusions and promoting the formation of a dense protective film. The steel containing 0.0047% RE achieved the best corrosion resistance. The corrosion product layers were mainly composed of γ-FeOOH, α-FeOOH, Fe 3 O 4 , and Fe(OH) 3 . The results of the kinetic model showed that the dissolution of the anode was the restricted link of the whole process. The lowest apparent corrosion rate constant k of the sample containing 0.0047% RE was 2.359 × 10 −4 μm/h in the soil simulation solution. The kinetic model could serve as a method to predict the service life of steel parts.

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“…The formation of carbides has important consequences for the corrosion and mechanical performance of steels [ 28 ]. In view of the corrosion resistance, the formation of Cr-rich carbides is undesirable, as it reduces the solute concentration of Cr, which is crucial to the corrosion performance [ 3 , 29 ]. In contrast, the formation of carbides is desirable in wear-intensive applications, e.g., in razor blades, in tools for plastic molding, or in turbine blades in power plants [ 30 , 31 , 32 , 33 , 34 ].…”

Section: Introductionmentioning

confidence: 99%

Influence of Carbon on the Microstructure Evolution and Hardness of Fe–13Cr–xC (x = 0–0.7 wt.%) Stainless Steel

et al. 2021

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The influence of carbon on the phase transformation behavior of stainless steels with the base chemical composition Fe–13Cr (wt.%), and carbon concentrations in the range of 0–0.7 wt.%, was studied at temperatures between −196 °C and liquidus temperature. Based on differential scanning calorimetry (DSC) measurements, the solidification mode changed from ferritic to ferritic–austenitic as the carbon concentration increased. The DSC results were in fair agreement with the thermodynamic equilibrium calculation results. In contrast to alloys containing nearly 0% C and 0.1% C, alloys containing 0.2–0.7% C exhibited a fully austenitic phase stability range without delta ferrite at high temperatures. Quenching to room temperature (RT) after heat treatment in the austenite range resulted in the partial transformation to martensite. Due to the decrease in the martensite start temperature, the fraction of retained austenite increased with the carbon concentration. The austenite fraction was reduced by cooling to −196 °C. The variation in hardness with carbon concentration for as-quenched steels with martensitic–austenitic microstructures indicated a maximum at intermediate carbon concentrations. Given the steady increase in the tetragonality of martensite at higher carbon concentrations, as confirmed by X-ray diffraction measurements, the variation in hardness with carbon concentration is governed by the amount and stability of austenite.

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Corrosion resistance of 13wt.% Cr martensitic stainless steels: Additively manufactured CX versus wrought Ni-containing AISI 420

Cited by 61 publications

References 45 publications

Synergistic Effect of Composite V₂O₅/Ca_0.17V₂O₅ Film Electrodes as High-Performance Cathodes of SIBs

Synergistic Effect of Composite V₂O₅/Ca_0.17V₂O₅ Film Electrodes as High-Performance Cathodes of SIBs

Corrosion behavior and kinetics model of rare earth low‐alloy steel in a soil simulation solution

Influence of Carbon on the Microstructure Evolution and Hardness of Fe–13Cr–xC (x = 0–0.7 wt.%) Stainless Steel

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Corrosion resistance of 13wt.% Cr martensitic stainless steels: Additively manufactured CX versus wrought Ni-containing AISI 420

Cited by 61 publications

References 45 publications

Synergistic Effect of Composite V2O5/Ca0.17V2O5 Film Electrodes as High-Performance Cathodes of SIBs

Synergistic Effect of Composite V2O5/Ca0.17V2O5 Film Electrodes as High-Performance Cathodes of SIBs

Corrosion behavior and kinetics model of rare earth low‐alloy steel in a soil simulation solution

Influence of Carbon on the Microstructure Evolution and Hardness of Fe–13Cr–xC (x = 0–0.7 wt.%) Stainless Steel

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Product

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Synergistic Effect of Composite V₂O₅/Ca_0.17V₂O₅ Film Electrodes as High-Performance Cathodes of SIBs

Synergistic Effect of Composite V₂O₅/Ca_0.17V₂O₅ Film Electrodes as High-Performance Cathodes of SIBs