Corrosion study of carbon steel in CO2 loaded solution of N-methyldiethanolamine and l-arginine mixtures

Talkhan, Ahmed Gomaa; Benamor, Abdelbaki; Nasser, Mustafa S.; Qiblawey, Hazim; El-Tayeb, Sayed; El-Marsafy, S. M.

doi:10.1016/j.jelechem.2019.02.008

Cited by 16 publications

(5 citation statements)

References 45 publications

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“…observed a decrease in the linear polarization resistance (LPR) between the electrode and electrolyte with increasing temperature. The reduction in LPR signifies an increase in corrosion current density, consequently leading to an escalation in the corrosion rate of carbon steel in the solution 30 …”

Section: Resultsmentioning

confidence: 99%

“…The reduction in LPR signifies an increase in corrosion current density, consequently leading to an escalation in the corrosion rate of carbon steel in the solution. 30 It is noteworthy that the corrosion rates of both materials tend to stabilize after 14 days. This can be attributed to the formation and coverage of a protective film layer on the metal surface, which reaches a more complete state after 2 weeks of immersion.…”

Section: Corrosion Rate Tested In Immersion Experimentsmentioning

confidence: 97%

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Corrosion performance of carbon/stainless steel in amine‐based solvents under different conditions for CO₂ chemical absorption process

Wang,

Fang,

Wang

et al. 2023

Greenhouse Gases

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The overall corrosion behavior of S304 stainless steel and A3 carbon steel in 30 wt.% MEA (monoethanolamine) and AMP/MEA (2‐amino‐2‐methyl‐1‐propanol / monoethanolamine) blended amine solutions at 40–100°C was investigated. The characterization analysis of the corroded material surfaces was performed, and the changes in the properties of both solvents after long‐term immersion corrosion were measured, including the accumulation of heat stable salts (HSS) and viscosity changes. The results of the long‐term immersion corrosion experiments showed that the corrosion rate of S304 stainless steel was significantly lower than that of A3 carbon steel in both amine solutions. However, the corrosion rate of both materials exhibited a similar trend, initially decreasing and then stabilizing over time. Due to the higher concentration of carbonate ions in the AMP/MEA system, it exhibited better overall corrosion resistance and degradation resistance compared to the MEA system. The main component of the corrosion product on carbon steel was identified as Fe2(OH)2CO3. The electrochemical test results showed that the corrosion current of S304 stainless steel was much smaller than that of A3 carbon steel, and its charge transfer resistance was much higher, indicating that it was less prone to electron loss in the organic amine solutions. Additionally, the AMP/MEA system exhibited superior corrosion resistance. © 2023 Society of Chemical Industry and John Wiley & Sons, Ltd.

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Section: Resultsmentioning

confidence: 99%

Section: Corrosion Rate Tested In Immersion Experimentsmentioning

confidence: 97%

Corrosion performance of carbon/stainless steel in amine‐based solvents under different conditions for CO₂ chemical absorption process

Wang,

Fang,

Wang

et al. 2023

Greenhouse Gases

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“…An increase in temperature promotes electrochemical reactions and transport of species (molecular diffusion), which declined rapidly when PE was inserted. [ 71 ]…”

Section: Resultsmentioning

confidence: 99%

“…An increase in temperature promotes electrochemical reactions and transport of species (molecular diffusion), which declined rapidly when PE was inserted. [71] In fact, under the experimental temperatures of 30°C and 60°C, the corrosion efficiency and corrosion rates of carbon steel in blank solution and PE-containing solution under CO 2 partial pressure of 10 bar are listed in Table 4. There is an increase in corrosion efficiency as the concentration of corrosion inhibitor increases under both temperatures.…”

Section: Ac Testmentioning

confidence: 99%

A theoretical and experimental study of phosphate ester inhibitors for AISI 1018 in carbon dioxide‐saturated 3.5 wt% NaCl solution

Vasques

Levy

Rodrigues

et al. 2021

Materials & Corrosion

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Phosphate ester was investigated as a corrosion inhibitor for AISI 1018 carbon steel in carbon dioxide‐saturated chloride solutions at different temperatures and pressures. The corrosion tests were realized by electrochemical techniques, weight loss measurements, bubble tests, and a high‐pressure/high‐temperature autoclave system. The corrosion tests demonstrated that the investigated molecule is an excellent corrosion inhibitor. The inhibiting effect is even bigger at high pressure and temperature than at atmospheric pressure and room temperature. The thermodynamic parameters were calculated and determined to obey the Langmuir isotherm. Polarization studies revealed that the evaluated inhibitor is a mixed type.

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“…[8][9][10] Among them, extra N-containing amino acids L-Lysine (Lys) and L-Arginine (Arg) have been introduced in many studies of metal corrosion inhibition. [11][12][13] Although with all advantages as mentioned above, inhibition performance of mild amino acids can be hard to meet the demand of corrosion inhibition. Fortunately, it has been reported previously that the inhibition efficiency of any substance can be improved if another synergistic compound is added.…”

Section: Introductionmentioning

confidence: 99%

Corrosion inhibition of amino acids for 316L stainless steel and synergistic effect of I⁻ ions: Experimental and theoretical studies

Zhao

Qian

Niu

2021

Materials & Corrosion

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The inhibition effect of amino acids L-lysine (Lys) and L-arginine (Arg), which serve as inhibition films for corrosion of 316L stainless steel in 0.5 M NaCl solution, is studied by electrochemical measurements. The adsorption of the inhibitor molecules on the steel surface is studied by Fourier transformed infrared spectroscopy (FTIR) and surface-enhanced Raman spectroscopy (SERS), accompanied by the characterization of the metal surface by scanning electron microscopy (SEM). All in all, Lys or Arg can obviously restrain the corrosion of 316L steel, while the inhibition efficiency is even higher with the assistance of I − ions. Arg always has better inhibition performance than Lys regardless of the addition of I − ions. FTIR and SERS confirm the adsorption of amino acids on the metal surface; at the same time, the morphology and protection effect of the inhibition films is clearly illustrated via SEM images. Thanks to all experimental measurements as mentioned above and theoretical calculations, a mechanism model is proposed to simulate the corrosion inhibition process of amino acids and the synergistic effect of I − ions on 316L steel.

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Corrosion study of carbon steel in CO2 loaded solution of N-methyldiethanolamine and l-arginine mixtures

Cited by 16 publications

References 45 publications

Corrosion performance of carbon/stainless steel in amine‐based solvents under different conditions for CO₂ chemical absorption process

Corrosion performance of carbon/stainless steel in amine‐based solvents under different conditions for CO₂ chemical absorption process

A theoretical and experimental study of phosphate ester inhibitors for AISI 1018 in carbon dioxide‐saturated 3.5 wt% NaCl solution

Corrosion inhibition of amino acids for 316L stainless steel and synergistic effect of I⁻ ions: Experimental and theoretical studies

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Corrosion study of carbon steel in CO2 loaded solution of N-methyldiethanolamine and l-arginine mixtures

Cited by 16 publications

References 45 publications

Corrosion performance of carbon/stainless steel in amine‐based solvents under different conditions for CO2 chemical absorption process

Corrosion performance of carbon/stainless steel in amine‐based solvents under different conditions for CO2 chemical absorption process

A theoretical and experimental study of phosphate ester inhibitors for AISI 1018 in carbon dioxide‐saturated 3.5 wt% NaCl solution

Corrosion inhibition of amino acids for 316L stainless steel and synergistic effect of I− ions: Experimental and theoretical studies

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Product

Resources

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Corrosion performance of carbon/stainless steel in amine‐based solvents under different conditions for CO₂ chemical absorption process

Corrosion performance of carbon/stainless steel in amine‐based solvents under different conditions for CO₂ chemical absorption process

Corrosion inhibition of amino acids for 316L stainless steel and synergistic effect of I⁻ ions: Experimental and theoretical studies