Cover Picture: Hollow Structured Transition Metal Phosphates and Their Applications (Chem. Rec. 8/2022)

Munkaila, Samira; Dahal, Rabin; Kokayi, Manzili; Jackson, Tatyana; Bastakoti, Bishnu Prasad

doi:10.1002/tcr.202280801

Cited by 2 publications

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“…[51,52] Synthesis of FeTiO 3 nanoparticles (NPs) employs bottom-up approach usually in the presence of surfactants to achieve segregated materials with high surface area and sometimes porous. [53][54][55] Most literature reviewed in this study used a bottom-up approach to fabricate NPs from their molecular or ionic precursors to the formation of crystals. The surfactants assist in controlling morphology and generating pores.…”

Section: Synthesis Of Iron Titanate-based Nanoparticlesmentioning

confidence: 99%

An Emerging Trend in the Synthesis of Iron Titanate Photocatalyst Toward Water Splitting

Ashie,

Kumar,

Bastakoti

2024

The Chemical Record

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Hydrogen gas is a prominent focus in pursuing renewable and clean alternative energy sources. The quest for maximizing hydrogen production yield involves the exploration of an ideal photocatalyst and the development of a simple, cost‐effective technique for its generation. Iron titanate has garnered attention in this context due to its photocatalytic properties, affordability, and non‐toxic nature. Over the years, different synthesis routes, different morphologies, and some modifications of iron titanate have been carried out to improve its photocatalytic performance by enhancing light absorption in the visible region, boosting charge carrier transfer, and decreasing recombination of electrons and holes. The use of iron titanate photocatalyst for hydrogen evolution reaction has seen an upward trend in recent times, and based on available findings, more can be done to improve the performance. This review paper provides a comprehensive overview of the fundamental principles of photocatalysis for hydrogen generation, encompassing the synthesis, morphology, and application of iron titanate‐based photocatalysts. The discussion delves into the limitations of current methodologies and present and future perspectives for advancing iron titanate photocatalysts. By addressing these limitations and contemplating future directions, the aim is to enhance the properties of materials fabricated for photocatalytic water splitting.

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Section: Synthesis Of Iron Titanate-based Nanoparticlesmentioning

confidence: 99%

An Emerging Trend in the Synthesis of Iron Titanate Photocatalyst Toward Water Splitting

Ashie,

Kumar,

Bastakoti

2024

The Chemical Record

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“…[9] In particular, the specific functionality of the hybrid SCs has superseded EDLC and pseudo SCs because of the hybrid composites. [10][11][12][13] In the recent past, the back-up background for hybrid electrodes has imperatively summoned to be highly flexible without compromising their hold up lattice profile strongly coordinated geometry refers to metal-organic framework (MOF), which might certainly be promising toward technological improvisation onto the electrodes stability performance @ higher cycles for SCs device applications. [14][15][16][17] Numerous research works on MOF-based transition metals (TM) based oxides, chalcogenides, and phosphides are found to be promising for hybrid supercapacitor (HSC) applications.…”

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confidence: 99%

Investigation of Benzene 1,4‐Dicarboxylic Acid MOF Linker Encapped Zinc Phosphate @ rGO‐Based Binder‐Free Electrode for Hybrid Supercapacitor Applications

Ravi

Vickraman

Raja

2023

Physica Status Solidi (a)

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Maneuvering, railing, capturing, harvesting, and storing of energy tractable from renewable and nonrenewable sources brings forth natural stumbling block, which necessitated the emergence of alternative resources rather electrochemical storage devices since 19 th /20 th centuries. [1] The portable electronic gadgets have demanded better performance in terms of two vital electrochemical components energy density (ED) and power density (PD). [2,3] The researchers have a tandem approach on these parameters depending upon the threshold for utility advented another energy (besides rechargeable batteries) storage device, namely, electrochemical capacitors or ultracapacitors or the commonality refers to the supercapacitors (SCs). [4,5] Then the perception of SCs has transcended based on their working mechanism presented their the elusive state of art as EDLC, pseudo, and hybrid SCs. [6,7] Consequently, the innovative methodology has been engineered on electrodes befitting for SCs (symmetric, asymmetric, and hybrid), and their physio-chemical intricacies have been evolved empirically so as to accomplish the basic requisites appropriately demanded for electrodes for the energy storage materials. [8] As far as the stability and higher specific capacitance are concerned on SCs with the specific reference to implicit electrodes implored, the researchers have come across transition metal oxides, nitrides, phosphides, chalcogenides, phosphates, and so on have been identified as suitable material matrices for electrodes of SCs. [9] In particular, the specific functionality of the hybrid SCs has superseded EDLC and pseudo SCs because of the hybrid composites. [10][11][12][13] In the recent past, the back-up background for hybrid electrodes has imperatively summoned to be highly flexible without compromising their hold up lattice profile strongly coordinated geometry refers to metal-organic framework (MOF), which might certainly be promising toward technological improvisation onto the electrodes stability performance @ higher cycles for SCs device applications. [14][15][16][17] Numerous research works on MOF-based transition metals (TM) based oxides, chalcogenides, and phosphides are found to be promising for hybrid supercapacitor (HSC) applications. [18][19][20] In this line, Shigeyuki et al. attempted zinc @ BDC and reported Cs of 245 F g À1 @ 1 A g À1 with binder. [21] The role of the binder is to hold on both current collector and the active material. The disadvantage of the binder is its electrochemical inactiveness and its unnecessary loading constitutes "the dead mass," which constricts the electrochemical activity of the active material that might be resulting in lower Cs which is not the requisite for SC device applications. The novelty of the present investigation is to enhance the Cs, ED, and cyclic stability of the requisite SCs device performance without using a binder and improving the active material's performance in the present investigation. However, PO 3À 4 coordinated TM-based MOF have not yet been explored. Th...

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Cover Picture: Hollow Structured Transition Metal Phosphates and Their Applications (Chem. Rec. 8/2022)

Cited by 2 publications

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An Emerging Trend in the Synthesis of Iron Titanate Photocatalyst Toward Water Splitting

An Emerging Trend in the Synthesis of Iron Titanate Photocatalyst Toward Water Splitting

Investigation of Benzene 1,4‐Dicarboxylic Acid MOF Linker Encapped Zinc Phosphate @ rGO‐Based Binder‐Free Electrode for Hybrid Supercapacitor Applications

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