CRC Handbook of Solubility Parameters and Other Cohesion Parameters

Barton, Allan F. M.

doi:10.1201/9781315140575

Cited by 540 publications

(834 citation statements)

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“…magnetic stirring to dissolve the PLA phase because acetone is a good solvent for PLA [28]. Then the residual blends were taken out of the solvent and examined using SEM.…”

Section: Scanning Electron Microscopy (Sem)mentioning

confidence: 99%

Optimising Ductility of Poly(Lactic Acid)/Poly(Butylene Adipate-co-Terephthalate) Blends Through Co-continuous Phase Morphology

et al. 2018

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This paper examines the effect of the melt viscosities of the two component polymers on the morphology and mechanical properties of a series of biodegradable polymer blends. Melt blended compounds of poly(lactic acid) (PLA) and poly(butylene adipate-co-terephthalate) (PBAT) are prepared and their melt viscosities, thermal properties, crystallinity, mechanical properties and phase morphology are investigated. From the relative melt viscosities of PLA and PBAT in the processing regime used in the study, it is possible to calculate the volume fraction at which a co-continuous phase structure is formed. The predicted value is 19 wt% of PBAT and this value is verified by the results of mechanical properties, where results for elongation-to-break show a dramatic rise from around 10% up to 300% in the composition range between 10 and 20 wt% of PBAT. The co-continuous phase structure is also validated by scanning electron microscopy. Graphical AbstractKeywords Poly(lactic acid) · Poly(butylene adipate-co-terephthalate) · Co-continuous phase · Biodegradable · Blends

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“…magnetic stirring to dissolve the PLA phase because acetone is a good solvent for PLA [28]. Then the residual blends were taken out of the solvent and examined using SEM.…”

Section: Scanning Electron Microscopy (Sem)mentioning

confidence: 99%

Optimising Ductility of Poly(Lactic Acid)/Poly(Butylene Adipate-co-Terephthalate) Blends Through Co-continuous Phase Morphology

et al. 2018

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“…MIBK has no a good solubility parameter for PMMA -17.2 (J 1/2 cm -3/2 ), which provides a difference greater than 1.5. In the case of using the mixture of MIBK-xylene, the solubility is the average of those of the pure solvents [17] . However, it is not just the type of solvent/polymer that influences the process.…”

Section: Resultsmentioning

confidence: 99%

Effect of solvents on the morphology of PMMA films fabricated by spin-coating

2017

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“…While melamine has comparatively high solubility in ethylene glycol, it also has extremely high hydrogen bonding capacity and viscosity making it a challenging candidate for use as a porogenic solvent (36) …”

Section: Solvation Of Melamine Into the Porogen And The Use Of Computmentioning

confidence: 99%

“…Computer modelling offers an accurate way to accelerate the selection process by creating a short list of candidates from larger libraries which may then be tested in the laboratory. In bulk imprinting, the template must be dissolved in the results, the apparent necessity to employ solvents of high polarity and hydrogen-bonding capacity must be assumed to be a significant source of disruption to the formation of high affinity template-FM complexes in the solution (36,37). …”

Section: Solvation Of Melamine Into the Porogen And The Use Of Computmentioning

confidence: 99%

Computational design of molecularly imprinted polymer for direct detection of melamine in milk

Bates

Busato

Piletska

et al. 2017

Separation Science and Technology

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A novel protocol for use of molecularly imprinted polymer (MIP) in analysis of melamine is presented. Design of polymer for melamine has been achieved using a combination of computational techniques and laboratory trials, the former greatly reducing the duration of the latter. The compatibility and concerted effect of monomers and solvents were also investigated and discussed. Two novel open source tools were presented which are: the online polymer calculator from mipdatabase.com and the application of the Gromacs modelling suite to determine the ideal stoichiometric ratio between template and functional monomer. A c c e p t e d M a n u s c r i p t 2

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CRC Handbook of Solubility Parameters and Other Cohesion Parameters

Cited by 540 publications

References 0 publications

Optimising Ductility of Poly(Lactic Acid)/Poly(Butylene Adipate-co-Terephthalate) Blends Through Co-continuous Phase Morphology

Optimising Ductility of Poly(Lactic Acid)/Poly(Butylene Adipate-co-Terephthalate) Blends Through Co-continuous Phase Morphology

Effect of solvents on the morphology of PMMA films fabricated by spin-coating

Computational design of molecularly imprinted polymer for direct detection of melamine in milk

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