Creating monolayers and thin films of a novel bis(alkyl) substituted asymmetrical polyoxotungstate, {[CH3(CH2)11Si]2OSiW11O39}4−using the Langmuir–Blodgett technique

Chambers, R. Carlisle; Atkinson, Elizabeth J.O.; McAdams, David; Hayden, Eric J.; Brown, Davida J. Ankeny

doi:10.1039/b307808f

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Surfactant-encapsulated Pom Cluster1

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Cited by 36 publications

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“…In contrast to this approach, [146]. This synthesis also yields an LB monolayer at the air-water interface that is stable and forms reversibly, as evident by the lack of hysteresis in compression-expansion cycles.…”

Section: Surfactant-encapsulated Pom Clustermentioning

confidence: 92%

Metallo-supramolecular modules as a paradigm for materials science

Kurth

2008

Science and Technology of Advanced Materials

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Metal ion coordination in discrete or extended metallo-supramolecular assemblies offers ample opportunity to fabricate and study devices and materials that are equally important for fundamental research and new technologies. Metal ions embedded in a specific ligand field offer diverse thermodynamic, kinetic, chemical, physical and structural properties that make these systems promising candidates for active components in functional materials. A key challenge is to improve and develop methodologies for placing these active modules in suitable device architectures, such as thin films or mesophases. This review highlights recent developments in extended, polymeric metallo-supramolecular systems and discrete polyoxometalates with an emphasis on materials science.

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Section: Surfactant-encapsulated Pom Clustermentioning

confidence: 92%