CrPd nanoparticles on NH2-functionalized metal-organic framework as a synergistic catalyst for efficient hydrogen evolution from formic acid

Alkylamine-Grafted Organic Semiconductors with Plasma-Induced Defects as Electron Promoters of CO-Resistant Pd-Based Nanoparticles for Efficient Light-Driven On-Demand H2 Generation

“…This broad diffraction peak was located between the characteristic peaks of Au, Pd, and Ni, which demonstrated the formation of an alloy. 50 The XPS results of AuPdNi/DCN-10-APTS showed that Si still existed with an atomic content of 4.33% after Ar etching and the NH x content increased in comparison with that in DCN-10 (Figure 3c,d). This indicated that APTS was tightly grafted to DCN-10 in the catalyst.…”

Nanopore‐Supported Metal Nanocatalysts for Efficient Hydrogen Generation from Liquid‐Phase Chemical Hydrogen Storage Materials

“…Following this work, different kinds of small metal NPs were anchored in the MIL‐101, which were applied for the H 2 generation from FA dehydrogenation reactions. [ 32–37 ] For example, bimetallic Ag–Pd NPs with different Ag/Pd ratios were immobilized into MIL‐101 supports through a solution infiltration method coupling with the reduction by NaBH 4 . [ 32 ] The particle size of Ag–Pd NPs in AgPd@MIL‐101 was about 2.7 nm, which was smaller than that of mesoporous cavities but larger than the windows of MIL‐101; this could effectively inhibit the metal migration to the outer surface and improve the durability during applications.…”

“…The best‐performing Pd–NH 2 ‐MIL‐125 catalyst exhibited a TOF value of 214 h −1 at 32 °C. Subsequently, using a similar strategy, several NH 2 ‐functionalized MOFs were used to immobilize small metal NPs, such as AuPd@NH 2 ‐MIL‐101, [ 37 ] CoAuPd@NH 2 ‐MIL‐101, [ 34,36 ] CrPd@NH 2 ‐MIL‐101, [ 35 ] and AgPd@NH 2 ‐UiO‐66. [ 38 ] These catalysts exhibited enhanced H 2 generation rates or/and high H 2 selectivities toward FA dehydrogenation than the corresponding counterparts in which metal NPs were supported on unfunctionalized MOF supports.…”

Magnetic Composite of γ-Fe2O3 Hollow Sphere and Palladium Doped Nitrogen-rich Mesoporous Carbon as a Recoverable Catalyst for C-C Coupling Reactions

“…In this regard a wide range of inorganic and organic substances have already been designed and employed for supporting dissimilar metal catalysts to create heterogeneous catalysts. Among these solid supports, magnetic nano compounds and mesoporous materials have attracted much attention because to their exceptional properties such as relaxed recovery and high surface area [15][16][17][18][19] . In this regard, to enhance the speci c surface area and decrease the content of active components, building a novel heterogeneous catalyst on a suitable metal support has been proposed.…”