2010
DOI: 10.1080/07370650903401254
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Crystal State of 1,3,5-Triamino-2,4,6-Trinitrobenzene (TATB) Undergoing Thermal Cycling Process

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Cited by 53 publications
(66 citation statements)
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“…Finally, Figure 8b demonstrates agreement between the evolving (001) pole density measured during the experiment and simulations employing our modified March model (thick red curve) using Equations (12) and (7). The material exponent m was used as an empirical free fitting parameter; the plot in Figure 8b depicts model results that employ a value of m = 3.…”
Section: Comparison Of Simulation and Experimental Resultsmentioning
confidence: 84%
“…Finally, Figure 8b demonstrates agreement between the evolving (001) pole density measured during the experiment and simulations employing our modified March model (thick red curve) using Equations (12) and (7). The material exponent m was used as an empirical free fitting parameter; the plot in Figure 8b depicts model results that employ a value of m = 3.…”
Section: Comparison Of Simulation and Experimental Resultsmentioning
confidence: 84%
“…The exact mechanism responsible for our timeevolvingo bservationsr emains elusive. Other research [12] suggests that TATB crystal fragmentation and repair occurs with thermal cycling, and there is ac hance this pertains to the time-based behavior we have observed.…”
Section: S Ummarymentioning
confidence: 58%
“…28 The differences must result from different thermal expansion coefficient and different crystal structures. On one hand, the thermal expansion coefficient of TATB crystal along the c-axis is 6 times as much as that of crystalline graphite, 12 and consequently TATB crystals undergo higher micro-strain during thermal treatment. On the other hand, TATB crystals are composed with small TATB molecules, which are connected by intermolecular hydrogen bond interactions, and can be easily broken by micro-strain under thermal treatment, while graphite crystals are overlapped with infinite-extended big graphite molecules, comprise with covalent bonded carbon atoms, which can hardly be broken by micro-strain.…”
Section: Resultsmentioning
confidence: 99%
“…When TATB crystals are compacted into cylinders, the micro-strain makes all crystals stable on their balance position. 17 With a high CTE, 12 TATB crystals will expand to larger dimension during heating process. However, many crystals have been compacted into one cylinder, and the expansion of one crystal will be constrained by the adjacent crystals.…”
Section: Resultsmentioning
confidence: 99%
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