Crystal structure and conductivity of the organometallic linear chain system (Et4N)[Ni(DMIT)2] and related compounds

Abstract

. (1987). Crystal structure and conductivity of the organometallic linear chain system (Et4N)[Ni(dmit)2] and related compounds. Synthetic Metals,, 745-750. DOI: 10.1016/0379-6779(87)90446-2 General rightsCopyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights.• Users may download and print one copy of any publication from the public portal for the purpose of private study or research.• You may not further distribute the material or use it for any profit-making activity or commercial gain • You may freely distribute the URL identifying the publication in the public portal ? Take down policyIf you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim.

Structures of tetramethylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)niccolate(III) andtetra-n-propylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)niccolate(III)

“…Crystal structures of (NEt4)[Ni(dmit)21 and (NBun)[Ni(dmit)21 have already been determined. The former is a one-dimensional zigzag chain with interchain distances > 3.8 A (Groeneveld, Schuller, Kramer, Haasnoot & Reedijk, 1986;Kramer, Groeneveld, Joppe, Brom, de Jongh & Reedijk, 1987). The latter is, according to the atomic positions given by Lindqvist, Andersen, Sieler, Steimecke & Hoyer (1982), a network of intermolecular sulfur interactions along the x and y axes with no contacts in the z direction.…”