Crystal structure of (6-bromo-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithioate

Abstract

In the title compound, C15H14BrNO3S2, the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.034 (2) Å, and the morpholine ring adopts a chair conformation. The dihedral angle between best plane through the 2H-chromene ring system and the morpholine ring is 86.32 (9)°. Intra­molecular C—H⋯S hydrogen bonds are observed. In the crystal, inversion-related C—H⋯S and C—H⋯O inter­actions generate R 2 2(10) and R 2 2(8) rings patterns, respectively. In addition, the crystal packing features π–π inter­actions between fused benzene rings [centroid–centroid distance = 3.7558 (12) Å].