Crystal structure of bis{4-methyl-2-((E)-((4-((E)-1-(ethoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ² N,O)}copper(II), C₃₆H₃₈CuN₄O₄

Abstract

C36H38CuN4O4, triclinic, P1̄, a = 8.492(2) Å, b = 9.574(2) Å, c = 10.512(2) Å, α = 100.170(7)°, β = 103.421(7)°, γ = 95.055(8)°, Z = 1, V = 810.8(3) Å3, Rgt(F) = 0.0418, wRref(F2) = 0.1193, T = 296(2) K.

Synthesis and crystal structure of bis(5-methyl-2-aldehyde-phenolato-κ2 O 1,O 2)copper(II), C16H14CuO4

“…The angles of O1-Cu1-O2 and O1-Cu1-O1 i are 93.89(5)°and 180.0°, respectively. All geometric parameters are within typical ranges [11,12].…”

Synthesis and crystal structure of bis{((E)-((4-((E)-1-(benzyloxyimino)ethyl)phenyl)imino)methyl)-2-phenolato-κ2 N,O}copper(II), C44H38CuN4O4

“…Oximes are an important class of ligands due to their metal complexes, which have been widely studied and some studies on this subject are already available [4,5]. Recently much attention is being focused on analytical reagents for the detection and determination of some metal ions [6], nonlinear optical materials field [7] and supramolecular architectures [8][9][10][11][12] etc.…”

Synthesis and crystal structure of bis{5-fluorine-2-(((4-(1-(methoxy-imino)ethyl)phenyl) imino)methyl)phenolato-κ2 N,O}copper(II), C32H28CuF2N4O4

“…Schiff base ligands have excellent coordination ability and can form complexes with various transition metals [7,8]. So far, we have designed and synthesized a series of bidentate Schiff base ligands [9][10][11]. Particular attention has been paid to the structural and spectroscopic properties of Schiff base type metal complexes [12][13][14].…”

“…The angles of N1-Cu1-O1 and N1-Cu1-O1 i are 90.74 (6) and 89.26(6), respectively. All geometric parameters are in the typical ranges [8][9][10]12].…”