Crystal structure of the salt bis(triethanolamine-κ4N,O,O′,O′′)cadmium bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Ashurov, Jamshid

doi:10.1107/s2056989016004515

Cited by 3 publications

(2 citation statements)

References 39 publications

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“…16,23 However, these bond lengths are shorter than those of the reported eight-coordinated complexes. 3,22 In addition, the bond angles between the Cd1 and O atoms vary between 55.12º (7) and 170.64º ( 9) in Table 2. The bond angles of the complex are normal compared with those of the related complexes.…”

Section: The Crystal Structure Of [Cd(isopht) (Tea)h 2 O]•3h 2 Omentioning

confidence: 99%

“…Triethanolamine (TEA) is a potential ligand that can interact with metal ions to form supramolecular complexes with different structures, and many coordination compounds containing TEA ligands have been reported for the last two decades. [1][2][3][4][5][6] TEA is also used as a pH regulator in cosmetology, as a corrosion inhibitor in metal-cutting fluids, as a curing agent for epoxy and rubber polymers, in adhesives, antistatic agents, or as a pharmaceutical intermediate. [7][8][9] TEA generally acts as the tri-or tetradentate ligand, but some metal complexes with mono-or bidentate TEA coordination modes are also known.…”

Section: Introductionmentioning

confidence: 99%

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A Novel Cd(II) Isophthalate Complex with Triethanolamine: Crystal Structure, Fluorescence and Antimicrobial Activity

Yolcu

Yurtcan

Çıtlakoğlu

2021

ACSi

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A mixed ligand Cd(II) complex [Cd(IsoPht)(TEA)H2O]·3H2O was synthesized for the first time by using isophthalic acid (H2IsoPht) and tetradentate triethanolamine (TEA) and characterized by X-ray single-crystal diffraction, FT-IR, and thermogravimetric analysis (TGA). This novel complex crystallizes in the triclinic system with P-1 space group and distorted monocapped trigonal prismatic geometry. The Cd(II) has seven coordinates with bidentate IsoPht, a TEA in the tetradentate mode, and an aqua ligand. The fluorescence properties of the Cd(II) complex and TEA ligand were investigated at room temperature. The present Cd(II) complex was also tested for its antimicrobial activity by in vitro agar diffusion method against some Gram-positive and Gram-negative bacteria and a fungus.

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Section: The Crystal Structure Of [Cd(isopht) (Tea)h 2 O]•3h 2 Omentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

A Novel Cd(II) Isophthalate Complex with Triethanolamine: Crystal Structure, Fluorescence and Antimicrobial Activity

Yolcu

Yurtcan

Çıtlakoğlu

2021

ACSi

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A general guide for adsorption of cadmium sulfide (CdS) quantum dots by successive ionic layer adsorption and reaction (SILAR) for efficient CdS-sensitized photoelectrochemical cells

Lee

Patil

et al. 2022

Applied Surface Science

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Crystal Structure and Hirshfeld Surface Analysis of Bis(Triethanolamine)Nickel(II) Dinitrate Complex and a Revelation of Its Characteristics via Spectroscopic, Electrochemical and DFT Studies Towards a Promising Precursor for Metal Oxides Synthesis

et al. 2020

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Metal complexes with chelating ligands are known as promising precursors for the synthesis of targeted metal oxides via thermal decomposition pathways. Triethanolamine (TEA) is a versatile ligand possessing a variety of coordination modes to metal ions. Understanding the crystal structure is beneficial for the rational design of the metal complex precursors. Herein, a bis(triethanolamine)nickel (II) dinitrate (named as Ni-TEA) crystal was synthesized and thoroughly investigated. X-ray crystallography revealed that Ni(II) ions adopt a distorted octahedral geometry surrounded by two neutral TEA ligands via two N and four O coordinates. Hirshfeld surface analysis indicated the major contribution of the intermolecular hydrogen-bonding between —OH groups of TEA in the crystal packing. Moreover, several O–H stretching peaks in Fourier transformed infrared spectroscopy (FTIR) spectra emphasizes the various chemical environments of —OH groups due to the formation of the hydrogen-bonding framework. The Density-functional theory (DFT) calculation revealed the electronic properties of the crystal. Furthermore, the Ni-TEA complex is presumably useful for metal oxide synthesis via thermal decomposition at a moderate temperature (380 °C). Cyclic voltammetry indicated the possible oxidative reaction of the Ni-TEA complex at a lower potential than nickel(II) nitrate and TEA ligand, highlighting its promising utility for the synthesis of mixed valence oxides such as spinel structures.

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Crystal structure of the salt bis(triethanolamine-κ⁴N,O,O′,O′′)cadmium bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Cited by 3 publications

References 39 publications

A Novel Cd(II) Isophthalate Complex with Triethanolamine: Crystal Structure, Fluorescence and Antimicrobial Activity

A Novel Cd(II) Isophthalate Complex with Triethanolamine: Crystal Structure, Fluorescence and Antimicrobial Activity

A general guide for adsorption of cadmium sulfide (CdS) quantum dots by successive ionic layer adsorption and reaction (SILAR) for efficient CdS-sensitized photoelectrochemical cells

Crystal Structure and Hirshfeld Surface Analysis of Bis(Triethanolamine)Nickel(II) Dinitrate Complex and a Revelation of Its Characteristics via Spectroscopic, Electrochemical and DFT Studies Towards a Promising Precursor for Metal Oxides Synthesis

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