Crystal structure, spectroscopy, DFT studies and thermal characterization of Cobalt(II) complex with 2-protonated aminopyridinium cation as ligand

Physico‐Chemical Properties, Pharmacokinetics, Molecular Docking and In‐Vitro Pharmacological Study of a Cobalt (II) Complex Based on 2‐Aminopyridine

“…The coordination compound (2‐HAMP) 2 [CoBr 4 ] was prepared in our laboratory [19] . Whereas the crystal structure of the compound has been previously reported, its physical and biological properties based on its crystal structure will be discussed in greater detail.…”

“…[18] In an attempt to study organic-inorganic complexes, a hybrid compound with the formula (C 5 H 7 N 2 ) 2 [CoBr 4 ] has been synthesized and its structure was determined. [19] The purpose of this paper is to investigate the phase transitions in (2-HAMP) 2 [CoBr 4 ] using calorimetric analysis. The synthesized complex has been studied electrochemically.…”

“…Molecular docking is one of the promising tools for drug discovery and development via the study of the intermolecular interactions of the targeted complex: ligand/drug molecules and the receptor, particularly its binding pocket [18] . In an attempt to study organic‐inorganic complexes, a hybrid compound with the formula (C 5 H 7 N 2 ) 2 [CoBr 4 ] has been synthesized and its structure was determined [19] . The purpose of this paper is to investigate the phase transitions in (2‐HAMP) 2 [CoBr 4 ] using calorimetric analysis.…”

Synthesis, structure and characterization of five new organically templated metal sulfates with 2-aminopyridinium

“…The crystal structure of bis(2-aminopyridinium) sulfate has also been reported (Jebas et al, 2006a). In the literature, there are reports where simple inorganic-organic hybrids with the 2ap cation and various halogen salts, characterized by interesting supramolecular networks (Luque et al, 1997;Su et al, 2002;Kumar et al, 2005;Jebas et al, 2006b;Zhang et al, 2006;Fun et al, 2008;Gelmboldt et al, 2009;Cai & Fu, 2010;Jin et al, 2011;Rao et al, 2011;Mhadhbi et al, 2016) and dielectric properties, are discussed (Kulicka et al, 2004). In general, protonated aminopyridinium cations act mainly as templating agents as they contribute directly to the dimensionality of the hydrogen-bonding network in the crystal structures of hybrid organic-inorganic materials.…”

Crystal structure and optical characterization of a new hybrid compound, C6H9N2FeCl4, with large dielectric constants for field-effect transistors

“…It is generally associated with a high chemical reactivity, and low kinetic stability and is also termed a so molecule. [52][53][54] The HOMO is the orbital that primarily acts as an electron donor and the LUMO is the orbital that largely acts as an electron acceptor. HOMO−2, HOMO−1, HOMO, LUMO, LUMO+1 and LUMO+2 molecular orbital isosurfaces along with their energy values are illustrated in Fig.…”