Crystal Structures and Polymorphism of Nickel and Copper Coordination Polymers with Pyridine Ligands

Abstract

The crystal structures of a series of pyridine coordination polymers [M II Cl 2 (C 5 H 5 N) x

Crystal structure of [bis(2-aminoethyl-κN)(2-{[4-(trifluoromethyl)benzylidene]amino}ethyl)amine-κN]dichloridocopper(II)

“…Of the 318 structures, none incorporates the trifluoromethyl-substituted phenyl group presented here and none displays the dichloride counterions presented here. A survey of Cu-Cl bond-length elongations of similar structures in the literature produced examples such as 2.6061 18and 2.609 (2) Å (Tucker et al, 1991), 2.843 (1) to 3.140 (1) Å (Krysiak et al, 2014), 2.665 3and 2.731 (2) Å (Ferrari et al, 1998) and 2.7546 (9) Å (Odoko et al, 2002).…”

Synthesis, Structures, Thermal and Luminescence Properties of Zn and Cd Halide Coordination Polymers with 2‐Cyanopyrazine

“…In general, this approach can be used for the synthesis of a wide range of compounds including not only transition metal thio‐ and selenocyanates but also transition metal halide coordination compounds with Cu I , Zn II , Cd II and other 3d cations , …”

“…[17,18] In general, this approach can be used for the synthesis of a wide range of compounds including not only transition metal thio-and selenocyanates but also transition metal halide coordination compounds with Cu I , Zn II , Cd II and other 3d cations. [11,[19][20][21][22][23][24][25][26] For compounds based on metal halides, different substructures are reported, in which the metal cations are linked by the halide anions into dimers, chains or layers. [27][28][29][30][31][32][33] For, e.g.…”

Syntheses and crystal structures of transition-metal bromide complexes with pyridine-type ligands: [MBr2(3-cypy)4] and [MBr2(3-cypy)2]n

“…Thermal decomposition induces the polymerization of these molecules: by release of two cyanopyridine molecules in the first step of thermal decomposition single chains are obtained where the M II -ions are linked by pairs of bridging bromide cations in order to maintain the octahedral coordination at the metal atom. Further decomposition steps lead to the formation of double chains, bands and larger two dimensional networks [2], [3].…”