Crystal supramolecular motifs. Ladders, layers and labyrinths of Ph4P+ cations engaged in fourfold phenyl embraces

Structure and Magnetism of 3D Anionic Metal Dicyanamide (MePh3P)[M(dca)3] (M = Fe, Co, Ni) and (EtPh3P)[M(dca)3] (M = Mn, Co, Ni) Networks

“…By use of the Dance notation, these are 5P1Y interactions. 21 The phenyl rings of the cations also display intercavity edge-to-face and vertex-to-face interactions.…”

Jahn-Teller distortion ofC60−in(Ph4As)2Long1, Schundler2, Adams3 et al. 2007Phys. Rev. B91200View full textAdd to dashboardCite

“…33,34,36,37 A nearly cubic symmetry embrace of phenyl rings encapsulates each C 60 − , 35 with offset face-to-face or edge-to-face attractive interactions between Ph rings and C 60 hexagons. 38 Since the fourfold crystallographic symmetry is not replicated in the I h point group, 39 there are two equivalent perpendicular orientations of the C 60 − cage that are randomly occupied. 34,36,37 Although both the disorder and the JT effect are reported to be static at low temperature, 36,40,41 no distortion of C 60 − in ͑Ph 4 X͒ 2 YC 60 has been detected by x-ray diffraction [34][35][36][37] or diffuse x-ray scattering, 42 and an upper bound of 0.01 Å has been set on deviations from an I h symmetry cage.…”

The Influence of Weak Interactions on Electric Conductivity of Silver Sulfobenzoate Complexes with Two Neutral Ligands

“…[28,29] Dance and Scudder have systemically investi-gated the functionalities of various phenyl embraces interactions containing phenyl, aryl, or hetero-aryl appendages, which certainly exists in Ag-PPh 3 complexes, generating some interesting features in the crystal packing and topologies. [30][31][32][33][34][35][36][37][38][39][40] The ligand PPh 3 will decrease or eliminate the π···π interactions in silver complexes.…”